Department of Environmental Analytics, Faculty of Chemistry, University of Gdansk, Gdansk, Poland.
Crit Rev Anal Chem. 2020;50(1):1-28. doi: 10.1080/10408347.2019.1565983. Epub 2019 Jun 15.
Aquatic passive samplers have been extensively tested and deployed in the field over the past two decades. Among these devices is relatively recently developed the Polar Organic Chemical Integrative Sampler (POCIS) for isolation of hydrophilic organic micropollutants in aquatic environment. The use of POCIS allows the measurement of low and fluctuating trace concentrations of such micropollutants, which is often troublesome using classical sampling. In this review, POCIS applications based on numerous articles to assess the suitability of these devices for use in environmental analytics information were summarized. Additionally, the possibilities of using POCIS for the isolation of complex chemical mixtures in order to highlight the high potential of this devices were presented. The types of sorbents used in POCIS, exposure duration and sampling media are juxtapose in this review. Based on the existing literature, attention was paid to both promising opportunities but also to limitations of passive methods.
在过去的二十年中,水相被动采样器在现场得到了广泛的测试和应用。在这些设备中,最近开发的极性有机化学整合采样器(POCIS)用于分离水相环境中的亲水性有机微量污染物。使用 POCIS 可以测量此类微量污染物的低浓度和波动浓度,这在使用传统采样时通常很麻烦。在这篇综述中,根据大量评估这些设备在环境分析中的适用性的文章,总结了 POCIS 的应用。此外,还介绍了使用 POCIS 分离复杂化学混合物的可能性,以突出该设备的高潜力。在这篇综述中,将 POCIS 中使用的吸附剂类型、暴露时间和采样介质并列。基于现有文献,既关注了被动方法的有前途的机会,也关注了其局限性。