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热退火诱导聚合物光催化剂的结构重组以增强析氢性能。

Thermal annealing-induced structural reorganization in polymeric photocatalysts for enhanced hydrogen evolution.

作者信息

Lan Zhi-An, Fang Yuanxing, Chen Xiong, Wang Xinchen

机构信息

State Key Laboratory of Photocatalysis on Energy and Environment, College of Chemistry, Fuzhou University, Fuzhou 350116, China.

出版信息

Chem Commun (Camb). 2019 Jul 2;55(54):7756-7759. doi: 10.1039/c9cc02966d.

Abstract

Herein, a facile reorganization of a triazine-based conjugated polymer structure was adopted to optimize the optical, electronic, and photocatalytic properties of the polymer. The optimal photocatalyst presents enhanced performance as compared to the pristine photocatalyst by a factor of 3. This demonstration provides a new strategy for the optimization of conjugated polymers for various photoredox applications.

摘要

在此,采用了一种基于三嗪的共轭聚合物结构的简便重组方法来优化该聚合物的光学、电子和光催化性能。与原始光催化剂相比,优化后的光催化剂性能提高了3倍。这一实例为优化用于各种光氧化还原应用的共轭聚合物提供了一种新策略。

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