Porous Organic Polymers Containing a Sulfur Skeleton for Visible Light Degradation of Organic Dyes.

Three novel chemically stable porous organic polymers (POPs) were synthesized by the hydrothermal method; the POPs contain sulfone bonds (TpSD), no sulfur atoms (TpMD), or thioether bonds (TpTD). The catalytic mechanism of the POP with sulfone bonds was studied, and it was found that the wide visible light absorption range, high specific surface area, and the hydrophilicity of the material significantly promoted the catalytic efficiency of TpSD. The presence of O=S=O gives TpSD a higher degree of conjugation than TpMD and TpTD, so TpSD shows the strongest UV/Visible absorption and faster transmission of electrons. The photocatalytic degradation of Rhodamine B (RhB) molecules is approximately 100 % with TpSD and its pseudo-first-order rate constant is 0.0770 min , which is the highest among all reported non-metallic photocatalysts. Moreover, it is also the first time that sulfur-containing polymer have been used in photocatalytic degradation of dyes.