手性对卟啉大环中紫精客体结合的影响。

Varghese Shaji, Spierenburg Bram, Bruekers Jeroen P J, Swartjes Anne, White Paul B, Elemans Johannes A A W, Nolte Roeland J M

Institute for Molecules and Materials Radboud University Heyendaalseweg 135 6525 AJ Nijmegen The Netherlands.

European J Org Chem. 2019 Jun 10;2019(21):3525-3533. doi: 10.1002/ejoc.201900221. Epub 2019 May 3.

As part of a project aimed at the development of chiral processive catalysts that can write information on a polymer chain we describe the synthesis of two optically active porphyrin macrocycles, which are prepared in 3 steps from an achiral precursor compound. Fluorescence and H-NMR studies show that one of the macrocycles displays selectivity in the binding of chiral viologen guest molecules.

作为一个旨在开发能够在聚合物链上写入信息的手性连续催化剂项目的一部分，我们描述了两种旋光卟啉大环化合物的合成，它们由一种非手性前体化合物分三步制备而成。荧光和氢核磁共振研究表明，其中一种大环化合物在手性紫精客体分子的结合方面表现出选择性。