Yang Xiao-Gang, Zhai Zhi-Min, Lu Xiao-Min, Zhao Ying, Chang Xin-Hong, Ma Lu-Fang
College of Chemistry and Chemical Engineering, Henan Province Function-Oriented Porous Materials Key Laboratory, Luoyang Normal University, Luoyang 471934, P. R. China.
Dalton Trans. 2019 Aug 7;48(29):10785-10789. doi: 10.1039/c9dt02178g. Epub 2019 Jun 27.
Room temperature phosphorescence of Mn(ii) and Zn(ii) based coordination polymers (Mn-CP and Zn-CP) with a different mechanism was confirmed by experiments and theory calculations. The Mn-CP exhibits high photoelectron response performance while Zn-CP can generate frequency tunable alternating current when the period of on-off illumination is changed.
通过实验和理论计算证实了具有不同机理的基于锰(II)和锌(II)的配位聚合物(Mn-CP和Zn-CP)的室温磷光。Mn-CP表现出高光电子响应性能,而当开-关照明周期改变时,Zn-CP可以产生频率可调的交流电。