带有N-氧化物和-NH的稠环：用于高密度和低灵敏度含能材料的良好组合。
Fused rings with N-oxide and -NH: good combination for high density and low sensitivity energetic materials.
作者信息
Hu Lu, Yin Ping, Imler Gregory H, Parrish Damon A, Gao Haixiang, Shreeve Jean'ne M
机构信息
Department of Chemistry, University of Idaho, Moscow, Idaho 83844-2343, USA.
Naval Research Laboratory, 4555 Overlook Avenue, Washington, D.C. 20375, USA.
出版信息
Chem Commun (Camb). 2019 Aug 7;55(61):8979-8982. doi: 10.1039/c9cc04496e. Epub 2019 Jul 10.
Oxidation reactions of 3,6-diamino-1,2,4-triazolo[4,3-b][1,2,4,5]tetrazine give four N-oxide compounds. Because of the presence of an amino group and the N-oxide moiety, these compounds are extensively hydrogen bonded. Resulting from π-π stacking interactions between the fused rings, compounds 1-3 are impact and friction insensitive, are thermally stable and have good density.
3,6-二氨基-1,2,4-三唑并[4,3-b][1,2,4,5]四嗪的氧化反应生成四种氮氧化物化合物。由于存在氨基和氮氧化物部分，这些化合物形成广泛的氢键。由于稠环之间的π-π堆积相互作用，化合物1-3对冲击和摩擦不敏感，热稳定性好且密度高。
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