4-硝基-1,2,3-三唑的氨化反应中的敏感能量学。
Sensitive Energetics from the -Amination of 4-Nitro-1,2,3-Triazole.
机构信息
Department of Materials Engineering, Department of Mechanical Engineering Purdue University West Lafayette IN 47904 USA.
Department of Chemical Engineering Purdue University 610 Purdue Mall West Lafayette IN 47907 USA.
出版信息
ChemistryOpen. 2020 May 8;9(8):806-811. doi: 10.1002/open.202000053. eCollection 2020 Aug.
Energetic N-amino-C-nitro compounds 1-amino-4-nitro-1,2,3-triazole and 2-amino-4-nitro-1,2,3-triazole are characterized for the first time as energetic materials. These compounds were characterized chemically by nuclear magnetic resonance (NMR), Infrared spectroscopy and X-ray crystallography. Compounds were also characterized energetically by differential scanning calorimetry (DSC), impact, and friction and found to possess sensitivities and performances classifying them as primary explosives with PETN-like performance.
首次将能量 N-氨-C-硝基化合物 1-氨基-4-硝基-1,2,3-三唑和 2-氨基-4-硝基-1,2,3-三唑鉴定为能量材料。这些化合物通过核磁共振 (NMR)、红外光谱和 X 射线晶体学进行了化学特性鉴定。化合物还通过差示扫描量热法 (DSC)、冲击、摩擦进行了能量特性鉴定，被发现具有敏感度和性能，将其归类为具有 PETN 性能的一级爆炸物。
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