Coordination Isomers of Trinuclear PtHg Complex That Differ in Type of Metal-Metal Bond.

作者信息

Yamaguchi Tadashi, Yoshiya Kohei

机构信息

Department of Chemistry and Biochemistry, School of Advanced Science and Engineering , Waseda University , Tokyo 169-8555 , Japan.

出版信息

Inorg Chem. 2019 Aug 5;58(15):9548-9552. doi: 10.1021/acs.inorgchem.9b00978. Epub 2019 Jul 17.

New type isomers that differ in metal-metal bond type are isolated. One is the Pt-Hg-Pt complex, which has two metal-metal covalent bonds, Pt-Hg = 2.5459(8) and 2.5483(7) Å, and the other is the Pt→Hg-Pt complex, which has one metal-metal covalent bond, Pt-Hg = 2.5744(6) Å, and one metal-metal dative bond, Pt→Hg = 2.6635(7) Å.