三丙胺促进的近红外区吡咯并吡咯 Aza-BODIPY 的高效电致化学发光：涉及 S 和 T 态的形成。
Efficient Electrogenerated Chemiluminescence of Pyrrolopyrrole Aza-BODIPYs in the Near-Infrared Region with Tripropylamine: Involving Formation of S and T States.
机构信息
Department of Applied Chemistry, Graduate School of Engineering , Kyushu University , 744 Motooka, Nishi-ku , Fukuoka 819-0395 , Japan.
Center for Molecular Systems (CMS) , Kyushu University , 744 Motooka, Nishi-ku , Fukuoka 819-0395 , Japan.
出版信息
J Am Chem Soc. 2019 Jul 31;141(30):11791-11795. doi: 10.1021/jacs.9b05245. Epub 2019 Jul 17.
Efficient electrogenerated chemiluminescences (ECLs) of three pyrrolopyrrole aza-BODIPYs in the near-infrared region by using tripropylamine as a coreactant are reported. Kinetic analysis based on Marcus theory indicates the direct formation of S and T states through the electron transfer reaction, which affects the ECL efficiencies.
本文报道了三吡咯并吡咯并氮杂 BODIPY 作为近红外区电致化学发光（ECL）的高效试剂，三丙胺作为共反应物。基于马库斯理论的动力学分析表明，电子转移反应直接形成 S 和 T 态，从而影响 ECL 效率。
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