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铜/氧化铜@氧化锌中空纳米纤维气体传感器:中空纳米纤维结构和P-N结对工作温度及灵敏度的影响

Cu/CuO@ZnO Hollow Nanofiber Gas Sensor: Effect of Hollow Nanofiber Structure and P-N Junction on Operating Temperature and Sensitivity.

作者信息

Hwang Sung-Ho, Kim Young Kwang, Hong Seong Hui, Lim Sang Kyoo

机构信息

Smart Textile Convergence Research Group, Daegu Gyeongbuk Institute of Science & Technology (DGIST), Daegu 42988, Korea.

出版信息

Sensors (Basel). 2019 Jul 17;19(14):3151. doi: 10.3390/s19143151.

DOI:10.3390/s19143151
PMID:31319601
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6679310/
Abstract

For the fast and easy detection of carbon monoxide (CO) gas, it was necessary to develop a CO gas sensor to operate in low temperatures. Herein, a novel Cu/CuO-decorated ZnO hollow nanofiber was prepared with the electrospinning, calcination, and photodeposition methods. In the presence of 100 ppm CO gas, the Cu/CuO-photodeposited ZnO hollow nanofiber (Cu/CuO@ZnO HNF) showed twice higher sensitivity than that of pure ZnO nanofiber at a relatively low working temperature of 300 °C. The hollow structure and p-n junction between Cu/CuO and ZnO would be considered to contribute to the enhancement of sensitivity to CO gas at 300 °C due to the improved specific surface area and efficient electron transfer.

摘要

为了快速简便地检测一氧化碳(CO)气体,有必要开发一种能在低温下工作的CO气体传感器。在此,采用静电纺丝、煅烧和光沉积方法制备了一种新型的Cu/CuO修饰的ZnO中空纳米纤维。在存在100 ppm CO气体的情况下,Cu/CuO光沉积的ZnO中空纳米纤维(Cu/CuO@ZnO HNF)在300°C的相对较低工作温度下,其灵敏度比纯ZnO纳米纤维高出两倍。由于比表面积的提高和有效的电子转移,Cu/CuO与ZnO之间的中空结构和p-n结被认为有助于提高在300°C下对CO气体的灵敏度。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/0f39c38fbbf0/sensors-19-03151-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/de135112b276/sensors-19-03151-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/7abb41339280/sensors-19-03151-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/ba2d83d1e628/sensors-19-03151-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/2860862829dc/sensors-19-03151-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/c7e0809e0c2a/sensors-19-03151-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/dbafa15e9912/sensors-19-03151-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/0f39c38fbbf0/sensors-19-03151-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/de135112b276/sensors-19-03151-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/7abb41339280/sensors-19-03151-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/ba2d83d1e628/sensors-19-03151-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/2860862829dc/sensors-19-03151-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/c7e0809e0c2a/sensors-19-03151-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/dbafa15e9912/sensors-19-03151-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/af82/6679310/0f39c38fbbf0/sensors-19-03151-g007.jpg

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