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由 ZnO 修饰的石墨烯氧化物纳米带组成的纳米复合材料,用于室温下对 NO 气体的电阻式传感。

A nanocomposite consisting of ZnO decorated graphene oxide nanoribbons for resistive sensing of NO gas at room temperature.

机构信息

Division of Interdisciplinary Research, Suzhou Institute of Nano-Tech and Nano-Bionics, Chinese Academy of Sciences, 215123, Suzhou, People's Republic of China.

School of Nano Technology and Nano Bionics, University of Science and Technology of China, 230026, Hefei, People's Republic of China.

出版信息

Mikrochim Acta. 2019 Jul 20;186(8):554. doi: 10.1007/s00604-019-3628-x.

Abstract

A composite prepared from zinc oxide and graphene oxide nanoribbons (ZnO/GONR) is demonstrated to enable improved room temperature (RT) detection of nitrogen dioxide (NO). Low-cost hydrothermal synthesis is used to construct the composite. The properties of the resistive sensor, including the sensitivity, response and recovery times, repeatability and selectivity, were investigated in the NO concentration range from 1 to 50 ppm at RT. The sensor, typically operated at a voltage of 5 V, exhibits a low detection limit of 1 ppm, a fast response-recovery time, and excellent repeatability which outperforms that of pure ZnO sensors. The sensing mechanism is explained in terms of a redox reaction between NO and oxygen anions on the surface of the ZnO/GONR composite. Graphical abstract Schematic representation of the NO sensing mechanisms on the surface of the ZnO/GONR composite and overall improved NO gas-sensing performance.

摘要

一种由氧化锌和石墨烯氧化物纳米带(ZnO/GONR)组成的复合材料被证明可以提高室温(RT)下对二氧化氮(NO)的检测能力。采用低成本的水热合成方法来构建复合材料。在 RT 下,NO 浓度范围为 1 至 50 ppm 时,研究了电阻式传感器的性能,包括灵敏度、响应和恢复时间、重复性和选择性。该传感器通常在 5 V 的电压下工作,具有低至 1 ppm 的检测限、快速的响应-恢复时间和出色的重复性,优于纯 ZnO 传感器。根据 NO 与 ZnO/GONR 复合材料表面氧阴离子之间的氧化还原反应,解释了传感机制。

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