Gulati Saumya, Hietsoi Oleksandr, Calvary Caleb A, Strain Jacob M, Pishgar Sahar, Brun Henry C, Grapperhaus Craig A, Buchanan Robert M, Spurgeon Joshua M
Conn Center for Renewable Energy Research, University of Louisville, Louisville, Kentucky 40292, USA.
Chem Commun (Camb). 2019 Aug 7;55(64):9440-9443. doi: 10.1039/c9cc04117f.
The molecular catalyst diacetyl-bis(N-4-methyl-3-thiosemi-carbazonato)nickel(ii) (NiATSM) was integrated with Si for light-driven hydrogen evolution from water. Compared to an equivalent loading of Ni metal, the NiATSM/p-Si electrode performed better. Durability of the surface-bound catalyst under operation in acid was achieved without covalent attachment by using Nafion binding.
分子催化剂二乙酰基双（N-4-甲基-3-硫代半卡巴腙）镍（II）（NiATSM）与硅集成，用于光驱动水制氢。与等量负载的镍金属相比，NiATSM/p-Si电极表现更佳。通过使用Nafion结合，在酸性条件下运行时，表面结合催化剂无需共价连接即可实现耐久性。
