Department of Chemistry, University of Pennsylvania, Philadelphia, PA, 19104, USA.
Chemistry. 2019 Dec 18;25(71):16171-16178. doi: 10.1002/chem.201902871. Epub 2019 Oct 11.
In the last seven years, chemistry of the phosphaethynolate reagent, Na(OCP)(1,4-dioxane) , has seen a surge in organic and inorganic chemistry-A renaissance to cyanate chemistry in a new guise. Whereas there have been many reports of main group reactivity with [OCP] , largely from group 14, in more recent times the use of electropositive metals has garnered significant interest given their ability to disguise in various oxidation states. Herein, we report and discuss advances in such studies of [OCP] with early transition metal and f-block metal scaffolds.
在过去的七年中，膦炔试剂 Na(OCP)(1,4-二氧六环)的化学性质在有机和无机化学领域引起了广泛关注——这是氰酸酯化学的一种新形式。虽然已经有很多关于[OCP]与主族元素反应的报道，主要来自第 14 族，但最近，由于它们能够在各种氧化态下伪装，使用正电性金属引起了人们的极大兴趣。在此，我们报告并讨论了早期过渡金属和 f 区金属支架与[OCP]的此类研究进展。
