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由碳纳米管/主链型聚苯并恶嗪复合材料轻松制备耐用超疏水薄膜。

Facile Fabrication of Durable Superhydrophobic Films from Carbon Nanotube/Main-Chain Type Polybenzoxazine Composites.

作者信息

Wang Chih-Feng, Wang Wen-Ning, Lin Ching-Hsuan, Lee Kuo-Jung, Hu Chien-Chieh, Lai Juin-Yih

机构信息

Graduate Institute of Applied Science and Technology, National Taiwan University of Science and Technology, Taipei 106, Taiwan.

Department of Materials Science and Engineering, I-Shou University, Kaohsiung 840, Taiwan.

出版信息

Polymers (Basel). 2019 Jul 14;11(7):1183. doi: 10.3390/polym11071183.

DOI:10.3390/polym11071183
PMID:31337137
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6680462/
Abstract

Superhydrophobic materials have immense applications in the fields of industry and research. However, their durability is still a cause for concern. A facile method for preparing durable superhydrophobic films from carbon nanotubes (CNTs) and the main-chain type polybenzoxazine precursors is reported herein. We used probe ultrasonicator to prepare CNT/polybenzoxazine coatings. Compared with the general sonicating dispersion process, the dispersion time was greatly reduced from a few hours to 5 minutes and the prepared suspension exhibited film-forming characteristics well. The CNT/polybenzoxazine films, which do not contain any fluorinated compounds, exhibit remarkable durability against thermal treatment, organic solvents, corrosive liquids, and sandpaper abrasion, while retaining their superhydrophobicity. Furthermore, these CNT/polybenzoxazine films also showed durable superhydrophobicity after ultraviolet (UV) irradiation for 100 h. This CNT/polybenzoxazine film can be readily used for practical applications to make durable superhydrophobic coatings.

摘要

超疏水材料在工业和研究领域有广泛应用。然而，它们的耐久性仍是一个令人担忧的问题。本文报道了一种由碳纳米管（CNT）和主链型聚苯并恶嗪前驱体制备耐用超疏水薄膜的简便方法。我们使用探针超声仪制备CNT/聚苯并恶嗪涂层。与一般的超声分散过程相比，分散时间从几小时大幅缩短至5分钟，且制备的悬浮液表现出良好的成膜特性。不含任何氟化物的CNT/聚苯并恶嗪薄膜在热处理、有机溶剂、腐蚀性液体和砂纸磨损方面表现出显著的耐久性，同时保持其超疏水性。此外，这些CNT/聚苯并恶嗪薄膜在紫外线（UV）照射100小时后也显示出持久的超疏水性。这种CNT/聚苯并恶嗪薄膜可很容易地用于实际应用中，以制备耐用的超疏水涂层。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/cda1197ab696/polymers-11-01183-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/47adac01ebc8/polymers-11-01183-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/db2cbf74911f/polymers-11-01183-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/cd8e5e46a67f/polymers-11-01183-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/26b8473c4170/polymers-11-01183-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/4b7299ac59c4/polymers-11-01183-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/e4803a83deb1/polymers-11-01183-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/cda1197ab696/polymers-11-01183-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/47adac01ebc8/polymers-11-01183-sch001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/db2cbf74911f/polymers-11-01183-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/cd8e5e46a67f/polymers-11-01183-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/26b8473c4170/polymers-11-01183-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/4b7299ac59c4/polymers-11-01183-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/e4803a83deb1/polymers-11-01183-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/9fc0/6680462/cda1197ab696/polymers-11-01183-g007.jpg

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本文引用的文献

1
Directional adhesion of superhydrophobic butterfly wings.超疏水蝴蝶翅膀的定向粘附
Soft Matter. 2007 Jan 23;3(2):178-182. doi: 10.1039/b612667g.
2
All-organic superhydrophobic coatings with mechanochemical robustness and liquid impalement resistance.具有机械化学稳定性和抗液体刺穿性的全有机超疏水涂层。
Nat Mater. 2018 Apr;17(4):355-360. doi: 10.1038/s41563-018-0044-2. Epub 2018 Mar 26.
3
A simple way to an ultra-robust superhydrophobic fabric with mechanical stability, UV durability, and UV shielding property.一种具有机械稳定性、耐紫外线和紫外线屏蔽性能的超坚固超疏水织物的简单方法。
聚合物-碳纳米管纳米复合材料中间相区域对网络性能影响的研究
Polymers (Basel). 2020 Jan 10;12(1):182. doi: 10.3390/polym12010182.
4
Calculation of the Electrical Conductivity of Polymer Nanocomposites Assuming the Interphase Layer Surrounding Carbon Nanotubes.假设围绕碳纳米管的界面层时聚合物纳米复合材料电导率的计算
Polymers (Basel). 2020 Feb 11;12(2):404. doi: 10.3390/polym12020404.
5
Development of Expanded Takayanagi Model for Tensile Modulus of Carbon Nanotubes Reinforced Nanocomposites Assuming Interphase Regions Surrounding the Dispersed and Networked Nanoparticles.假设围绕分散和网络化纳米颗粒存在界面区域的情况下，用于碳纳米管增强纳米复合材料拉伸模量的扩展高柳模型的开发。
Polymers (Basel). 2020 Jan 17;12(1):233. doi: 10.3390/polym12010233.
6
Simulation of Percolation Threshold, Tunneling Distance, and Conductivity for Carbon Nanotube (CNT)-Reinforced Nanocomposites Assuming Effective CNT Concentration.假设有效碳纳米管浓度下碳纳米管（CNT）增强纳米复合材料的渗流阈值、隧穿距离和电导率模拟
Polymers (Basel). 2020 Jan 5;12(1):114. doi: 10.3390/polym12010114.
7
Biodegradable Polylactide/TiO Composite Fiber Scaffolds with Superhydrophobic and Superadhesive Porous Surfaces for Water Immobilization, Antibacterial Performance, and Deodorization.具有超疏水和超粘附多孔表面的可生物降解聚丙交酯/TiO复合纤维支架用于水固定、抗菌性能和除臭
Polymers (Basel). 2019 Nov 11;11(11):1860. doi: 10.3390/polym11111860.
J Colloid Interface Sci. 2018 Jul 15;522:57-62. doi: 10.1016/j.jcis.2018.03.038. Epub 2018 Mar 13.
4
Rough Structure of Electrodeposition as a Template for an Ultrarobust Self-Cleaning Surface.电沉积的粗糙结构作为超坚固自清洁表面的模板。
ACS Appl Mater Interfaces. 2017 May 17;9(19):16571-16580. doi: 10.1021/acsami.6b15745. Epub 2017 May 2.
5
Robust and Superhydrophobic Surface Modification by a "Paint + Adhesive" Method: Applications in Self-Cleaning after Oil Contamination and Oil-Water Separation.通过“涂料+胶黏剂”法实现坚固且超疏水表面改性：在油污自清洁和油水分离方面的应用。
ACS Appl Mater Interfaces. 2016 Jul 13;8(27):17659-67. doi: 10.1021/acsami.6b04108. Epub 2016 Jun 28.
6
Ultra-Durable and Transparent Self-Cleaning Surfaces by Large-Scale Self-Assembly of Hierarchical Interpenetrated Polymer Networks.通过分层互穿聚合物网络的大规模自组装制备超耐用和透明的自清洁表面。
ACS Appl Mater Interfaces. 2016 Jun 1;8(21):13615-23. doi: 10.1021/acsami.6b03414. Epub 2016 May 20.
7
Mechanically robust, thermally stable, broadband antireflective, and superhydrophobic thin films on glass substrates.玻璃基板上具有机械坚固性、热稳定性、宽带抗反射性和超疏水性的薄膜。
ACS Appl Mater Interfaces. 2014 Jun 25;6(12):9029-35. doi: 10.1021/am5016777. Epub 2014 Jun 5.
8
Low-surface-free-energy materials based on polybenzoxazines.基于聚苯并恶嗪的低表面自由能材料。
Angew Chem Int Ed Engl. 2006 Mar 27;45(14):2248-51. doi: 10.1002/anie.200503957.
9
Biophysics: water-repellent legs of water striders.生物物理学：水黾的拒水腿。
Nature. 2004 Nov 4;432(7013):36. doi: 10.1038/432036a.
10
Liquid morphologies on structured surfaces: from microchannels to microchips.结构化表面上的液体形态：从微通道到微芯片
Science. 1999 Jan 1;283(5398):46-9. doi: 10.1126/science.283.5398.46.