二并苯[cde,opq]苉的合成与晶体结构。
Synthesis and Crystal Structure of Dimorphic Dibenzo[cde,opq]rubicene.
机构信息
Fakultät Chemie, Technische Universität Dresden, Bergstrasse 66, 01069, Dresden, Germany.
Fachbereich Chemie, Philipps-Universität Marburg, Hans-Meerwein-Strasse 4, 35043, Marburg, Germany.
出版信息
Chemistry. 2019 Oct 28;25(60):13759-13765. doi: 10.1002/chem.201902915. Epub 2019 Sep 24.
Abstract
Dibenzo[cde,opq]rubicene has been synthesized by an eight-step reaction sequence including an iron-mediated [2+2+1] cycloaddition and a flash vacuum pyrolysis as key steps. Two crystal modifications of the S-shaped, planar polycyclic aromatic hydrocarbon have been obtained and characterized by X-ray diffractometry.
摘要
二苯并[cde,opq]苝通过包括铁介导的 [2+2+1] 环加成和闪光真空热解在内的八步反应序列合成。已经获得了两种 S 形平面多环芳烃的晶型，并通过 X 射线衍射法进行了表征。
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