Improved Derivation of the Butler Equations for Surface Tension of Solutions.

The Butler equation was published in 1932 to describe the equilibrium surface composition and equilibrium surface tension of solutions. Unfortunately, it used the so-called "partial surface tension of a component", which was not properly defined by Butler, leading to a reluctant acceptance of this equation. Although the present author defined the partial surface tension recently in this journal, it is considered an advantage to derive the same key equations of Butler without the need to employ the concept of partial surface tension. This derivation is offered in the present paper, starting from the two fundamental equations of Gibbs. No assumptions are made on the thickness and structure of the surface region, it is only supposed that the surface region has an average composition with a negligible concentration gradient. In this way, the Butler equations are obtained, which have more general validity compared to the original Butler equations derived by supposing a surface monolayer.