温和实用的二价铑（II）/NHPI 介导的空气氧化烯丙基和苄基反应。
Mild and Practical Dirhodium(II)/NHPI-Mediated Allylic and Benzylic Oxidations with Air as the Oxidant.
机构信息
Key Laboratory of Green Chemistry & Technology of Ministry of, Education, College of Chemistry, Sichuan University, Chengdu, 610064, P.R. China.
Key Laboratory of Bio-Resource and Eco-Environment of Ministry of, Education, College of Life Sciences, Sichuan University, Chengdu, 610064, P.R. China.
出版信息
Chemistry. 2019 Nov 13;25(63):14273-14277. doi: 10.1002/chem.201902739. Epub 2019 Sep 24.
Aerobic allylic and benzylic oxidations catalyzed by dirhodium(II) complexes with N-hydroxyphthalimide (NHPI) are described. The open flask reaction occurs at mild temperature, using air as the oxidant. Mechanistic studies suggest that dirhodium(II) complexes axially coordinate with NHPI to activate the O-H bond in NHPI and decrease the bond-dissociation energy (BDE).
有氧烯丙基和苄基氧化反应由二钌(II)配合物与 N-羟基邻苯二甲酰亚胺（NHPI）催化。该开瓶反应在温和的温度下进行，使用空气作为氧化剂。机理研究表明，二钌(II)配合物轴向与 NHPI 配位，从而激活 NHPI 中的 O-H 键，并降低键离解能（BDE）。
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