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钆和钴共掺杂钇铁氧体纳米粉末的结构、磁性和光学性质

Structural, Magnetic and Optical Properties of Gd and Co Co-Doped YFeO Nanopowders.

作者信息

Wang Meng, Wang Ting

机构信息

School of Mechanical and Electrical Engineering, Shenzhen Polytechnic, Shenzhen 518055, China.

Shenzhen Key Laboratory of Advanced Materials, Department of Materials Science and Engineering, Shenzhen Graduate School, Harbin Institute of Technology, Shenzhen 518055, China.

出版信息

Materials (Basel). 2019 Jul 30;12(15):2423. doi: 10.3390/ma12152423.

Abstract

YFeO, YFeCoO, YGdFeO and YGdFeCoO (x = 0.0, 0.05, 0.10, 0.15 and 0.20) nanopowders were successfully fabricated via a low-temperature solid-state reaction technique. Results obtained using X-ray diffraction (XRD), scanning electron microscopy (SEM), and Raman spectra indicate that YFeO nanopowders with Gd and Co ions co-doping at Y and Fe-sites were fabricated at 800 °C in sizes below 50 nm, and a distorted structure was obtained. Magnetic hysteresis loop analyses illustrate that ferromagnetic behavior of YFeO nanopowders can be enhanced with the addition of Gd and Co. Whereas the maximum and remnant magnetization of the powders were found to be about 5.24 and 2.6 emu/g, respectively, the optical band gap was around 2.4 eV, proving that co-doped YFeO nanopowders have a strong capability to absorb visible light. Because both magnetic and optical properties of these materials are greatly improved with the addition of Gd and Co, one can expect the scope of their potential application in the magnetic and optical fields to increase.

摘要

通过低温固态反应技术成功制备了YFeO、YFeCoO、YGdFeO和YGdFeCoO(x = 0.0、0.05、0.10、0.15和0.20)纳米粉末。使用X射线衍射(XRD)、扫描电子显微镜(SEM)和拉曼光谱获得的结果表明,在Y和Fe位点共掺杂Gd和Co离子的YFeO纳米粉末在800°C下制备,尺寸小于50 nm,并获得了扭曲结构。磁滞回线分析表明,添加Gd和Co可以增强YFeO纳米粉末的铁磁行为。粉末的最大磁化强度和剩余磁化强度分别约为5.24和2.6 emu/g,光学带隙约为2.4 eV,证明共掺杂的YFeO纳米粉末具有很强的吸收可见光的能力。由于添加Gd和Co后这些材料的磁性能和光学性能都得到了极大改善,因此可以预期它们在磁学和光学领域的潜在应用范围将会扩大。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/7498/6696207/bf25c566a94b/materials-12-02423-g001.jpg

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