Electrohydrogenation of Carbon Dioxide using a Ternary Pd/Cu O-Cu Catalyst.

A simple one-pot method has been developed to synthesize a palladium/cuprous oxide-copper (Pd/Cu O-Cu) material with a well-defined structure, by modification of Cu O-Cu with Pd through a galvanic replacement reaction. Compared with the well-known copper/cuprous oxide (Cu/Cu O) catalysts, the Pd/Cu O-Cu material can catalyze the electroreduction of CO into C products with much higher faradaic efficiencies at lower overpotentials in a CO -saturated 0.5 m NaHCO solution. In particular, the highest faradaic efficiencies of 92 % for formate and 30 % for methane were achieved at -0.25 and -0.65 V (vs. the reversible hydrogen electrode), respectively. The improvement is suggested to be the result of a synergistic effect between PdH and the catalytically active copper sites during electrochemical CO reduction.