Reimer V, Wegewijs M R, Nestmann K, Pletyukhov M
Institute for Theory of Statistical Physics, RWTH Aachen, Aachen, Germany.
J Chem Phys. 2019 Jul 28;151(4):044101. doi: 10.1063/1.5094412.
To extend the classical concept of Markovianity to an open quantum system, different notions of the divisibility of its dynamics have been introduced. Here, we analyze this issue by five complementary approaches: equations of motion, real-time diagrammatics, Kraus-operator sums, as well as time-local and nonlocal (Nakajima-Zwanzig) quantum master equations. As a case study featuring several types of divisible dynamics, we examine in detail an exactly solvable noninteracting fermionic resonant level coupled arbitrarily strongly to a fermionic bath at an arbitrary temperature in the wideband limit. In particular, the impact of divisibility on the time-dependence of the observable level occupation is investigated and compared with typical Markovian approximations. We find that the loss of semigroup-divisibility is accompanied by a prominent reentrant behavior: Counter to intuition, the level occupation may temporarily increase significantly in order to reach a stationary state with smaller occupation, implying a reversal of the measurable transport current. In contrast, the loss of the so-called completely positive divisibility is more subtly signaled by the prohibition of such current reversals in specific time-intervals. Experimentally, it can be detected in the family of transient currents obtained by varying the initial occupation. To quantify the nonzero footprint left by the system in its effective environment, we determine the exact time-dependent state of the latter as well as related information measures such as entropy, exchange entropy, and coherent information.
为了将马尔可夫性的经典概念扩展到开放量子系统,人们引入了其动力学可分性的不同概念。在此,我们通过五种互补方法分析这个问题:运动方程、实时图解法、克劳斯算子求和,以及时间局部和非局部(中岛 - 兹万齐格)量子主方程。作为一个具有几种可分动力学类型的案例研究,我们详细研究了一个在宽带极限下任意温度下与费米子库任意强耦合的精确可解非相互作用费米子共振能级。特别地,研究了可分性对可观测量能级占据时间依赖性的影响,并与典型的马尔可夫近似进行了比较。我们发现半群可分性的丧失伴随着显著的重入行为:与直觉相反,能级占据可能会暂时显著增加,以便达到占据较小的稳态,这意味着可测量的输运电流会反转。相比之下,所谓的完全正可分性的丧失则更微妙地表现为在特定时间间隔内禁止这种电流反转。在实验中,可以在通过改变初始占据获得的瞬态电流族中检测到这种情况。为了量化系统在其有效环境中留下的非零痕迹,我们确定了后者精确的时间相关状态以及相关的信息度量,如熵、交换熵和相干信息。