Corrosion Detection by Infrared Attenuated Total Reflection Spectroscopy via Diamond-Like Carbon-Coated Silicon Wafers and Iron-Sensitive Dyes.

The durability of metal-based constructions, especially those containing reinforced concrete, is mainly limited by corrosion processes. Diamond-like carbon (DLC)-coated silicon (Si) wafers provide a chemically inert and mechanically robust sensing interface for application in aggressive environments. In this study, iron-sensitive dyes, i.e., 2,3-dihydroxypyridine (DHP) and 1,2-dihydroxybenzol (DHB), were coated onto DLC-modified Si wafers for evaluating the potential of detecting corrosion processes via evanescent field absorption spectroscopy using Fourier-transform infrared spectroscopy. The obtained IR spectra reveal discernible changes of the dye layer after exposure to iron solutions, which indicates that indeed corrosion processes may be studied at molecular level detail.