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微小拉伸应变对类金刚石碳涂层腐蚀性能的影响

Microtensile strain on the corrosion performance of diamond-like carbon coating.

作者信息

Lee Seung-Hwan, Kim Jung-Gu, Choi Heon-Woong, Lee Kwang-Ryeol

机构信息

Department of Advanced Materials Engineering, Sungkyunkwan University, 300 Chunchun-Dong, Jangan-Gu, Suwon 440-746, Korea.

出版信息

J Biomed Mater Res A. 2008 Jun 1;85(3):808-14. doi: 10.1002/jbm.a.31597.

Abstract

Hydrogenated diamond-like carbon films (a-C:H DLC) were deposited on STS 304 substrates for the fabrication of vascular stents by means of the r.f. plasma-assisted chemical vapor deposition technique. This study provides reliable and quantitative data for the assessment of the effect of strain on the corrosion performance of DLC-coated systems in the simulated body fluid obtained through electrochemical techniques (potentiodynamic polarization test and electrochemical impedance spectroscopy) and surface analysis (scanning electron microscopy). The electrolyte used in this test was 0.89% NaCl solution at pH 7.4 and 37 degrees C. It was found that the corrosion resistance of the plastically deformed DLC coating was insufficient for use as a protective film in a corrosive body environment. This is due to the increase in the delamination area and degradation of the substrate's corrosion properties with increasing tensile deformation.

摘要

通过射频等离子体辅助化学气相沉积技术,在用于制造血管支架的STS 304基底上沉积氢化类金刚石碳膜(a-C:H DLC)。本研究通过电化学技术(动电位极化测试和电化学阻抗谱)和表面分析(扫描电子显微镜),为评估应变对DLC涂层系统在模拟体液中的腐蚀性能的影响提供了可靠的定量数据。本测试中使用的电解质是pH值为7.4、温度为37℃的0.89% NaCl溶液。研究发现,塑性变形的DLC涂层的耐腐蚀性不足以在腐蚀性人体环境中用作保护膜。这是由于随着拉伸变形的增加,分层面积增大且基底的腐蚀性能下降。

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