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钛网-膜组件减小了流动电极电容去离子的电荷传递距离,提高了脱盐性能。

Decreased charge transport distance by titanium mesh-membrane assembly for flow-electrode capacitive deionization with high desalination performance.

机构信息

State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing, 100084, PR China.

State Key Joint Laboratory of Environment Simulation and Pollution Control, School of Environment, Tsinghua University, Beijing, 100084, PR China.

出版信息

Water Res. 2019 Nov 1;164:114904. doi: 10.1016/j.watres.2019.114904. Epub 2019 Jul 23.

Abstract

This study employed a titanium mesh-membrane assembly (MMA) as the current collector in flow-electrode capacitive deionization (FCDI) device (designated as M-FCDI), and obtained a much reduced charge transport distance as compared to traditional FCDI with plate-shaped current collectors located far from the exchange membrane. The average salt removal rate of M-FCDI was greatly improved by 76% under 10 wt% carbon content than the control experiment with graphite plate as current collector, and the charge efficiency remained over 75% even under low carbon loading. This improvement was attributed to the reduced resistance as revealed by electrochemical impedance spectroscopy tests. Further investigation on FCDI's performance with different specifications of titanium meshes showed that the implementation of MMA could provide a larger effective electron transfer area, which would lead to better desalting performance.

摘要

本研究采用钛网-膜组件(MMA)作为集流器,在流电极电容去离子(FCDI)装置中(命名为 M-FCDI),与传统的 FCDI 相比,其集流器为远离交换膜的平板状,可大大缩短电荷传输距离。在 10wt%碳含量下,与以石墨板为集流器的对照实验相比,M-FCDI 的平均脱盐率提高了 76%,即使在低碳负荷下,电荷效率仍保持在 75%以上。这种改进归因于电化学阻抗谱测试所揭示的电阻降低。进一步研究不同规格钛网的 FCDI 性能表明,MMA 的实施可以提供更大的有效电子传递面积,从而带来更好的脱盐性能。

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