以菲咯啉衍生物作为发光体的有机发光二极管研究。

Studies on Organic Light Emitting Diodes Using Phenanthroline Derivatives as Emitters.

作者信息

Pak Soyoung, Park Jinho, Lee Song Eun, Kim Young Kwan, Yoon Seung Soo

机构信息

Department of Chemistry, Sungkyunkwan University, Suwon, 440-746, Korea.

Department of Information Display, Hongik University, Seoul, 121-791, Korea.

出版信息

J Nanosci Nanotechnol. 2020 Jan 1;20(1):573-578. doi: 10.1166/jnn.2020.17232.

DOI:10.1166/jnn.2020.17232

PMID:31383213

Abstract

In this study, we designed and synthesized blue emitting materials based on 1, 10-phenanthroline derivatives. OLED devices using these materials were fabricated in the following sequence; indium-tin-oxide (ITO) (180 nm)/,'-diphenyl-,'-(2-napthyl)-(1,1'-phenyl)-4,4'-diamine (NPB) (50 nm)/Tris(4-carbazoyl-9-ylphenyl)amine (TCTA) (10 nm)/Blue materials (20 nm)/2,2',2″-(1,3, 5-Benzinetriyl)-tris(1-phenyl-1--benzimidazole) (TPBi) (30 nm)/lithium quinolate (Liq) (2 nm)/Al (100 nm). Particularly, a device using 2-(4-(9,9-dimethylacridin-10(9H)-yl)phenyl)-1-phenyl-1Himidazo[ 4,5-f][1,10] phenanthroline as a blue emitter showed the maximum values of luminous efficiency, power efficiency, and external quantum efficiency of 1.45 cd/A, 1.52 lm/W, 0.99%, respectively with the Commission Internationale d'Énclairage (CIE) () coordinates of (0.16, 0.14) at 8.0 V.

摘要

在本研究中，我们基于1,10 - 菲咯啉衍生物设计并合成了蓝色发光材料。使用这些材料的有机发光二极管（OLED）器件按以下顺序制备：氧化铟锡（ITO）（180纳米）/N,N'-二苯基-N,N'-二（2-萘基）-（1,1'-联苯）-4,4'-二胺（NPB）（50纳米）/三（4-咔唑-9-基苯基）胺（TCTA）（10纳米）/蓝色材料（20纳米）/2,2',2''-（1,3,5-苯三嗪）-三（1-苯基-1H-苯并咪唑）（TPBi）（30纳米）/喹啉酸锂（Liq）（2纳米）/铝（Al）（100纳米）。特别地，使用2-（4-（9,9-二甲基吖啶-10（9H）-基）苯基）-1-苯基-1H-咪唑并[4,5-f][1,10]菲咯啉作为蓝色发射体的器件在8.0伏时，发光效率、功率效率和外量子效率的最大值分别为1.45坎德拉/安培、1.52流明/瓦、0.99%，国际照明委员会（CIE）色坐标为（0.16, 0.14）。