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用于有机发光二极管的喹啉取代蒽衍生物的合成及电致发光性能

Synthesis and Electroluminescent Properties of Quinoline-Substituted Anthracene Derivatives for Organic Light-Emitting Diodes.

作者信息

Kim Changmin, Kang Jisu, Hwang Namhee, Lee Song Eun, Kim Young Kwan, Yoon Seung Soo

出版信息

J Nanosci Nanotechnol. 2018 Oct 1;18(10):7105-7109. doi: 10.1166/jnn.2018.15473.

DOI:10.1166/jnn.2018.15473
PMID:29954541
Abstract

In this study, two anthracene derivatives with quinoline moieties were synthesized. To investigate their electroluminescent (EL) properties, multilayered OLEDs with the following sequence; indiumtin-oxide (ITO)/N, N'-di(1-naphthyl)-N, N'-diphenyl-(1,1'-biphenyl)-4,4'-diamine (NPB) (20 nm)/Blue emitting materials (30 nm)/bathophenanthroline (Bphen) (30 nm)/lithium quinolate (Liq) (2 nm)/Al (100 nm) were fabricated using these materials as emitters. Two devices exhibited EL in blue to sky-blue regions. Especially, a device using 2,3-diphenyl-6-(10-(naphthalen-7-yl)anthracen-9-yl)quinoline (1) as an emitting material exhibited blue emission with a luminous efficiency, a power efficiency, an external quantum efficiency, and Commission International de L'Eclairage (CIE) coordinates of 1.01 cd/A, 0.43 lm/W, 0.80% at 20 mA/cm2, and (0.17, 0.22) at 6.0 V, respectively.

摘要

在本研究中,合成了两种带有喹啉部分的蒽衍生物。为了研究它们的电致发光(EL)特性,制备了具有以下结构的多层有机发光二极管;氧化铟锡(ITO)/N,N'-二(1-萘基)-N,N'-二苯基-(1,1'-联苯)-4,4'-二胺(NPB)(20纳米)/蓝色发光材料(30纳米)/红菲绕啉(Bphen)(30纳米)/喹啉酸锂(Liq)(2纳米)/铝(100纳米),使用这些材料作为发光体。两个器件在蓝色到天蓝色区域均表现出电致发光。特别地,一个使用2,3-二苯基-6-(10-(萘-7-基)蒽-9-基)喹啉(1)作为发光材料的器件在20毫安/平方厘米时表现出蓝色发射,其发光效率、功率效率、外量子效率以及国际照明委员会(CIE)坐标分别为1.01坎德拉/安培、0.43流明/瓦、0.80%,在6.0伏时为(0.17, 0.22)。

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