• 文献检索
  • 文档翻译
  • 深度研究
  • 学术资讯
  • Suppr Zotero 插件Zotero 插件
  • 邀请有礼
  • 套餐&价格
  • 历史记录
应用&插件
Suppr Zotero 插件Zotero 插件浏览器插件Mac 客户端Windows 客户端微信小程序
定价
高级版会员购买积分包购买API积分包
服务
文献检索文档翻译深度研究API 文档MCP 服务
关于我们
关于 Suppr公司介绍联系我们用户协议隐私条款
关注我们

Suppr 超能文献

核心技术专利:CN118964589B侵权必究
粤ICP备2023148730 号-1Suppr @ 2026

文献检索

告别复杂PubMed语法,用中文像聊天一样搜索,搜遍4000万医学文献。AI智能推荐,让科研检索更轻松。

立即免费搜索

文件翻译

保留排版,准确专业,支持PDF/Word/PPT等文件格式,支持 12+语言互译。

免费翻译文档

深度研究

AI帮你快速写综述,25分钟生成高质量综述,智能提取关键信息,辅助科研写作。

立即免费体验

泡沫铜上的富乙炔碳骨架作为共轭聚合物光阴极用于高效稳定的水还原。

Acetylenic carbon-rich frameworks on copper foam as conjugated polymer photocathodes for efficient and stable water reduction.

作者信息

Zhou Xue, Yang Jing, Zhang Zhonghai

机构信息

Shanghai Key Laboratory of Green Chemistry and Chemical Processes, School of Chemistry and Molecular Engineering, East China Normal University, Shanghai 200241, China.

出版信息

Chem Commun (Camb). 2019 Aug 27;55(70):10396-10399. doi: 10.1039/c9cc05497a.

DOI:10.1039/c9cc05497a
PMID:31386707
Abstract

In this communication, a carbon-rich poly(1,3,5-triethynylbenzene) (PTEB) nanofiber is synthesized via a Cu-surface mediated Glaser polycondensation on a copper foam (CF) surface. The PTEB/CF based photocathodes present a record-high and stable photocurrent density of -1.09 mA cm-2, more than 100 times higher than the previously reported results.

摘要

在本通讯中,通过在泡沫铜(CF)表面上的铜表面介导的格拉泽缩聚反应合成了富含碳的聚(1,3,5-三乙炔基苯)(PTEB)纳米纤维。基于PTEB/CF的光阴极呈现出创纪录的高且稳定的光电流密度-1.09 mA cm-2,比先前报道的结果高出100多倍。

相似文献

1
Acetylenic carbon-rich frameworks on copper foam as conjugated polymer photocathodes for efficient and stable water reduction.泡沫铜上的富乙炔碳骨架作为共轭聚合物光阴极用于高效稳定的水还原。
Chem Commun (Camb). 2019 Aug 27;55(70):10396-10399. doi: 10.1039/c9cc05497a.
2
Copper-surface-mediated synthesis of acetylenic carbon-rich nanofibers for active metal-free photocathodes.铜表面介导的炔烃富碳纳米纤维的合成及其作为活性无金属光阴极
Nat Commun. 2018 Mar 19;9(1):1140. doi: 10.1038/s41467-018-03444-0.
3
A carbon-rich nanofiber framework based on a conjugated arylacetylene polymer for photocathodic enzymatic bioanalysis.一种基于共轭芳基乙炔聚合物的富碳纳米纤维框架用于光阴极酶促生物分析。
RSC Adv. 2019 Dec 23;9(72):42533-42542. doi: 10.1039/c9ra09157b. eCollection 2019 Dec 18.
4
Molecular Engineering of Conjugated Acetylenic Polymers for Efficient Cocatalyst-free Photoelectrochemical Water Reduction.用于高效无共催化剂光电化学水还原的共轭乙炔聚合物的分子工程
Angew Chem Int Ed Engl. 2019 Jul 22;58(30):10368-10374. doi: 10.1002/anie.201904978. Epub 2019 Jun 25.
5
Copper-Surface-Mediated Synthesis of sp Carbon-Conjugated Covalent Organic Framework Photocathodes for Photoelectrochemical Hydrogen Evolution.铜表面介导合成用于光电化学析氢的sp碳共轭共价有机骨架光阴极
Chemistry. 2024 Dec 13;30(70):e202402930. doi: 10.1002/chem.202402930. Epub 2024 Oct 29.
6
Conjugated Acetylenic Polymers Grafted Cuprous Oxide as an Efficient Z-Scheme Heterojunction for Photoelectrochemical Water Reduction.共轭炔烃聚合物接枝氧化铜作为用于光电化学水还原的高效Z型异质结
Adv Mater. 2020 Oct;32(39):e2002486. doi: 10.1002/adma.202002486. Epub 2020 Aug 20.
7
Thiophene-Based Conjugated Acetylenic Polymers with Dual Active Sites for Efficient Co-Catalyst-Free Photoelectrochemical Water Reduction in Alkaline Medium.用于碱性介质中高效无共催化剂光电化学水还原的具有双活性位点的噻吩基共轭炔聚合物。
Angew Chem Int Ed Engl. 2021 Aug 16;60(34):18876-18881. doi: 10.1002/anie.202104469. Epub 2021 Jul 14.
8
Stable and Efficient CuO Based Photocathode through Oxygen-Rich Composition and Au-Pd Nanostructure Incorporation for Solar-Hydrogen Production.富氧组成和 Au-Pd 纳米结构掺入稳定高效的氧化铜基光阴极用于太阳能制氢。
ACS Appl Mater Interfaces. 2017 Aug 23;9(33):27596-27606. doi: 10.1021/acsami.7b02685. Epub 2017 Aug 8.
9
Gradient Self-Doped CuBiO with Highly Improved Charge Separation Efficiency.梯度自掺杂 CuBiO,可极大提高电荷分离效率。
J Am Chem Soc. 2017 Oct 25;139(42):15094-15103. doi: 10.1021/jacs.7b07847. Epub 2017 Oct 17.
10
Highly Active Three-Dimensional NiFe/Cu O Nanowires/Cu Foam Electrode for Water Oxidation.用于水氧化的高活性三维镍铁/氧化铜纳米线/泡沫铜电极
ChemSusChem. 2017 Apr 10;10(7):1475-1481. doi: 10.1002/cssc.201601884. Epub 2017 Feb 28.

引用本文的文献

1
Hydrogen-substituted graphdiyne encapsulated cuprous oxide photocathode for efficient and stable photoelectrochemical water reduction.用于高效稳定光电化学水还原的氢取代石墨二炔封装氧化亚铜光阴极
Nat Commun. 2022 Oct 1;13(1):5770. doi: 10.1038/s41467-022-33445-z.