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电加速作用下横向裂缝对混凝土中氯离子扩散及钢筋腐蚀行为的影响

Effects of Transverse Crack on Chloride Ions Diffusion and Steel Bars Corrosion Behavior in Concrete under Electric Acceleration.

作者信息

Du Fengyin, Jin Zuquan, Xiong Chuansheng, Yu Yong, Fan Junfeng

机构信息

College of Civil Engineering, Qingdao University of Technology, Qingdao 266033, China.

Cooperative Innovation Center of Engineering Consrtuction and Safety in Shandong Blue Economic Zone, Qingdao 266033, China.

出版信息

Materials (Basel). 2019 Aug 5;12(15):2481. doi: 10.3390/ma12152481.

Abstract

Cracks greatly impact the durability of concrete structures due to their influence on the migration of chloride ions and the corrosion process of steel bars. This study investigates the effects of transverse cracks on chloride diffusion and the corrosion behavior of two types of steel bars (low carbon steel and corrosion resistant steel) in fly ash concrete with 1 kg/m solution-polymerized super absorbent polymer. Electrochemical impedance spectroscopy was used to monitor the chloride-induced corrosion behavior of steel bars in concrete. The chloride profile around cracks was tested via chemical titration. The corrosion products diffusion area was photographed and measured to evaluate the influences of cracks on the corrosion degree of steel bars. Transverse cracks greatly influence the chloride ion transport. When their width is less than 0.15 mm, cracks exert little influence on both chloride diffusion and steel corrosion. When the crack width exceeds 0.15 mm, the chloride ion transmission coefficient is significantly improved and steel corrosion is accelerated. However, when the crack width exceeds 0.20 mm, this effect is gradually weakened. Based on the experimental data, a quantitative relationship between the crack width and the chloride ion transmission coefficient in electric acceleration was established.

摘要

裂缝对氯离子迁移和钢筋腐蚀过程有影响,极大地影响混凝土结构的耐久性。本研究调查了横向裂缝对氯离子扩散的影响以及在含有1 kg/m溶液聚合超吸水性聚合物的粉煤灰混凝土中两种类型钢筋(低碳钢和耐腐蚀钢)的腐蚀行为。采用电化学阻抗谱监测混凝土中钢筋的氯离子诱导腐蚀行为。通过化学滴定测试裂缝周围的氯离子分布。拍摄并测量腐蚀产物扩散面积以评估裂缝对钢筋腐蚀程度的影响。横向裂缝对氯离子传输有很大影响。当裂缝宽度小于0.15 mm时,裂缝对氯离子扩散和钢筋腐蚀的影响很小。当裂缝宽度超过0.15 mm时,氯离子传输系数显著提高,钢筋腐蚀加速。然而,当裂缝宽度超过0.20 mm时,这种影响逐渐减弱。基于实验数据,建立了电加速下裂缝宽度与氯离子传输系数之间的定量关系。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/5d80/6696064/a6c48135ee6c/materials-12-02481-g001.jpg

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