对“观察类过渡金属的碱土金属配合物 M(CO)（M = Ca、Sr 或 Ba）”一文的评论的回应。
Response to Comment on "Observation of alkaline earth complexes M(CO) (M = Ca, Sr, or Ba) that mimic transition metals".
机构信息
Institute of Advanced Synthesis, School of Chemistry and Molecular Engineering, Jiangsu National Synergetic Innovation Center for Advanced Materials, Nanjing Tech University, Nanjing 211816, China.
Fachbereich Chemie, Philipps-Universität Marburg, D-35043 Marburg, Germany.
出版信息
Science. 2019 Aug 9;365(6453). doi: 10.1126/science.aay5021. Epub 2019 Aug 8.
PMID:31395758
Abstract
Landis claim in their comment that Ca does not bind like a transition metal in Ca(CO) We reject their statement, which is based on a misconception of bonding models and misleading application and interpretation of quantum chemical methods for analyzing chemical bonds.
摘要
兰迪斯等人在评论中声称，钙在 Ca(CO) 中不具有过渡金属的结合方式。我们反对他们的说法，这是基于对成键模型的误解以及对分析化学键的量子化学方法的错误应用和解释。
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