Schwarz Benjamin, Dürr Maximilian, Kastner Katharina, Heber Nora, Ivanović-Burmazović Ivana, Streb Carsten
Institute of Inorganic Chemistry I , Ulm University , Albert-Einstein-Allee 11 , 89081 Ulm , Germany.
Chair of Bioinorganic Chemistry , Friedrich-Alexander-University Erlangen-Nuernberg , Egerlandstr. 1 , 91058 Erlangen , Germany.
Inorg Chem. 2019 Sep 3;58(17):11684-11688. doi: 10.1021/acs.inorgchem.9b01665. Epub 2019 Aug 15.
We report the polymerization of a solvent-stabilized molecular strontium vanadium oxide monomer into infinite 1D chains. Supramolecular polymerization is triggered by controlled solvent-exchange, which leads to oligomer and polymer formation. Mechanistic insights into the chain formation were obtained by solid-state, solution, and gas-phase studies. The study shows how reactivity control of molecular metal oxides can be used to assemble complex inorganic polymeric structures.
我们报道了一种溶剂稳定的分子型锶钒氧化物单体聚合成无限一维链的过程。超分子聚合由可控的溶剂交换引发，这导致了低聚物和聚合物的形成。通过固态、溶液和气相研究获得了对链形成的机理认识。该研究展示了如何利用分子金属氧化物的反应性控制来组装复杂的无机聚合物结构。
