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氧化铟锡/聚[2-甲氧基-5-(2'-乙基己氧基)-1,4-苯撑乙烯]:聚环氧乙烷:双(三氟甲基磺酰)亚胺锂/铝聚合物发光电化学电池中的磁电致发光

Magneto-Electroluminescence in ITO/MEH-PPV:PEO:LiCFSO/Al Polymer Light-Emitting Electrochemical Cells.

作者信息

Zhu Mingpeng, Yuan Xueting, Ni Gang

机构信息

Department of Optical Science and Engineering, Fudan University, Shanghai 200433, China.

Shanghai Engineering Research Center for Ultra-Precision Optical Manufacturing, Fudan University, Shanghai 200433, China.

出版信息

Micromachines (Basel). 2019 Aug 17;10(8):546. doi: 10.3390/mi10080546.

DOI:10.3390/mi10080546
PMID:31426537
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6723417/
Abstract

Magnetic field effects (MFE) have been extensively studied in organic light emitting diodes because of their potential application in organic spintronics devices. However, only a few studies on MFE in organic light-emitting electrochemical cells (LEC) have been reported. In this paper, magnetic field effects on the electroluminescence of an LEC device with the structure of ITO/MEH-PPV:PEO:LiCFSO/Al were studied at various temperatures. The luminance-current-voltage curves of the device shows the typical bi-polar characteristics of LECs; positive magnetic electroluminescence (MEL) was observed with a value of about 2.5% (B = 42 mT, 250 K), showing a Lorentzian line shape. With a decrease in temperature, the MEL value and the threshold voltage increased accordingly, below the possible mechanism is discussed.

摘要

由于磁场效应(MFE)在有机自旋电子器件中的潜在应用,其在有机发光二极管中已得到广泛研究。然而,关于有机发光电化学电池(LEC)中MFE的研究报道却很少。本文研究了在不同温度下,磁场对具有ITO/MEH-PPV:PEO:LiCFSO/Al结构的LEC器件电致发光的影响。该器件的亮度-电流-电压曲线呈现出LEC典型的双极特性;观察到正向磁电致发光(MEL),其值约为2.5%(B = 42 mT,250 K),呈现出洛伦兹线型。随着温度降低,MEL值和阈值电压相应增加,下面讨论其可能的机制。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/856e/6723417/807d8058f939/micromachines-10-00546-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/856e/6723417/f93700374e7c/micromachines-10-00546-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/856e/6723417/74c80bd1991a/micromachines-10-00546-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/856e/6723417/0412678a502b/micromachines-10-00546-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/856e/6723417/b8faed827c7d/micromachines-10-00546-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/856e/6723417/807d8058f939/micromachines-10-00546-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/856e/6723417/f93700374e7c/micromachines-10-00546-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/856e/6723417/74c80bd1991a/micromachines-10-00546-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/856e/6723417/0412678a502b/micromachines-10-00546-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/856e/6723417/b8faed827c7d/micromachines-10-00546-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/856e/6723417/807d8058f939/micromachines-10-00546-g005.jpg

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