Department of Chemistry , Indian Institute of Technology Madras , Chennai 600036 , Tamil Nadu , India.
J Org Chem. 2019 Sep 6;84(17):10679-10689. doi: 10.1021/acs.joc.9b01223. Epub 2019 Aug 20.
[]-Face π-expanded coumarins are synthesized by employing the Scholl cyclization method. These new arene-annulated dipolar coumarins display interesting absorption and fluorescent properties. The large Stokes shifts, tuneable fluorescent quantum yields, and high photostability reveal promise in bioimaging application.
[ ]-Face π-扩展香豆素是通过 Scholl 环化方法合成的。这些新的芳环稠合偶极香豆素表现出有趣的吸收和荧光性质。大斯托克斯位移、可调谐荧光量子产率和高光稳定性使其在生物成像应用中具有广阔的前景。
