School of Chemistry, Monash University, Clayton, VIC, 3800, Australia.
ARC Centre of Excellence for Electromaterials Science, Monash University, Clayton, VIC, 3800, Australia.
ChemSusChem. 2020 Jan 9;13(1):59-77. doi: 10.1002/cssc.201901794. Epub 2019 Oct 10.
Two-dimensional (2D) materials are attractive catalysts for the electrochemical reduction of carbon dioxide reaction (eCO RR) by virtue of their tunable atomic structures, abundant active sites, enhanced conductivity, suitable binding affinity to carbon dioxide and/or reaction intermediates, and intrinsic scalability. Herein, recent advances in 2D catalysts for the eCO RR are reviewed. Structural features and properties of 2D materials that contribute to their advanced electrocatalytic properties are summarized, and strategies for enhancing their activity and selectivity for the eCO RR are reviewed. Prospects and challenges of applications of 2D catalysts for the eCO RR on an industrial scale are highlighted.
二维（2D）材料因其可调的原子结构、丰富的活性位点、增强的导电性、对二氧化碳和/或反应中间体的合适结合亲和力以及内在的可扩展性，成为电化学还原二氧化碳反应（eCO RR）的有吸引力的催化剂。本文综述了二维催化剂在 eCO RR 中的最新进展。总结了 2D 材料的结构特征和性质对其先进电催化性能的贡献，并综述了提高其对 eCO RR 的活性和选择性的策略。强调了二维催化剂在工业规模上应用于 eCO RR 的前景和挑战。
