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阻燃天然纤维/埃lium复合材料的燃烧性、烟雾、力学行为及形态

Flammability, Smoke, Mechanical Behaviours and Morphology of Flame Retarded Natural Fibre/Elium Composite.

作者信息

Khalili Pooria, Blinzler Brina, Kádár Roland, Bisschop Roeland, Försth Michael, Blomqvist Per

机构信息

Material and Computational Mechanics, Department of Industrial and Materials Science, Chalmers University of Technology, 412 96 Gothenburg, Sweden.

Division of Engineering Materials, Department of Industrial and Materials Science, Chalmers University of Technology, 412 96 Gothenburg, Sweden.

出版信息

Materials (Basel). 2019 Aug 21;12(17):2648. doi: 10.3390/ma12172648.

Abstract

The work involves fabrication of natural fibre/Elium composites using resin infusion technique. The jute fabrics were treated using phosphorus-carbon based flame retardant (FR) agent, a phosphonate solution and graphene nano-platelet (GnP), followed by resin infusion, to produce FR and graphene-based composites. The properties of these composites were compared with those of the Control (jute fabric/Elium). As obtained from the cone calorimeter and Fourier transform infrared spectroscopy, the peak heat release rate reduced significantly after the FR and GnP treatments of fabrics whereas total smoke release and quantity of carbon monoxide increased with the incorporation of FR. The addition of GnP had almost no effect on carbon monoxide and carbon dioxide yield. Dynamic mechanical analysis demonstrated that coating jute fabrics with GnP particles led to an enhanced glass transition temperature by 14%. Scanning electron microscopy showed fibre pull-out locations in the tensile fracture surface of the laminates after incorporation of both fillers, which resulted in reduced tensile properties.

摘要

这项工作涉及使用树脂灌注技术制造天然纤维/埃利姆复合材料。黄麻织物先用磷碳基阻燃剂(FR)、膦酸盐溶液和石墨烯纳米片(GnP)进行处理,然后进行树脂灌注,以生产基于FR和石墨烯的复合材料。将这些复合材料的性能与对照组(黄麻织物/埃利姆)的性能进行了比较。从锥形量热仪和傅里叶变换红外光谱获得的数据表明,对织物进行FR和GnP处理后,峰值热释放速率显著降低,而随着FR的加入,总烟雾释放量和一氧化碳量增加。添加GnP对一氧化碳和二氧化碳产量几乎没有影响。动态力学分析表明,用GnP颗粒包覆黄麻织物可使玻璃化转变温度提高14%。扫描电子显微镜显示,在加入两种填料后,层压板拉伸断裂表面出现纤维拔出位置,这导致拉伸性能降低。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/6425/6747569/ab8cf216f67b/materials-12-02648-g001.jpg

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