Tuong Vu Manh, Huyen Nguyen Van, Kien Nguyen Trong, Dien Nguyen Van
College of Wood Industry and Interior Design, Vietnam National University of Forestry, Ha Noi 156200, Vietnam.
Polymers (Basel). 2019 Aug 23;11(9):1388. doi: 10.3390/polym11091388.
The hydrophobicity and color stability of wood are important properties that can be easily changed when wood is used as a raw material for outdoor products, reducing the service life of wood. Herein, an epoxy@ZnO coating was applied by a two-step simple spray coating method to improve the hydrophobicity and color stability of wood. The hydrophobicity, robustness of coating, as well as the color stability of uncoated wood samples and epoxy@ZnO coated wood samples were evaluated. The microstructure morphology and crystal structures of the coating were also characterized by a field-emission scanning electron microscope (FESEM) and X-ray diffraction (XRD) analysis, respectively. Results showed that the obtained epoxy@ZnO coating was not only superhydrophobic with an average water contact angle of 154.1°, but also maintained superhydrophobicity with an average water contact angle of 149.6° after five water jetting tests. The color stability of the coated wood samples was improved by around 50% compared to that of uncoated wood samples. Additionally, a continuous epoxy@ZnO coating with hierarchical micro/nanoscale structures constructed by the wurtzite hexagonal structure of ZnO micro/nanoparticles on wood surfaces was confirmed.
木材的疏水性和颜色稳定性是重要特性,当木材用作户外产品的原材料时,这些特性很容易改变,从而缩短木材的使用寿命。在此,通过两步简单喷涂法施加环氧@ZnO涂层,以提高木材的疏水性和颜色稳定性。对未涂层木材样品和环氧@ZnO涂层木材样品的疏水性、涂层的坚固性以及颜色稳定性进行了评估。还分别用场发射扫描电子显微镜(FESEM)和X射线衍射(XRD)分析对涂层的微观结构形态和晶体结构进行了表征。结果表明,所获得的环氧@ZnO涂层不仅具有超疏水性,平均水接触角为154.1° ,而且在经过五次喷水测试后仍保持超疏水性,平均水接触角为149.6° 。与未涂层木材样品相比,涂层木材样品的颜色稳定性提高了约50%。此外,证实了在木材表面由ZnO微米/纳米颗粒的纤锌矿六方结构构建的具有分级微/纳米结构的连续环氧@ZnO涂层。