Vanathi V, Mullainathan S, Nithiyanatham S, Ramasamy V, Palaniappan L
Department of Physics, A.V.C. College of Engineering, Mannampandal, Mayiladuthurai, Tamilnadu, 609305, India.
P.G and Research Department of Physics, Thiru.Vi.Ka.Goverment Arts College, Thiruvarur, Tamilnadu, 610003, India.
Heliyon. 2019 Aug 14;5(8):e02203. doi: 10.1016/j.heliyon.2019.e02203. eCollection 2019 Aug.
Ultrasonic velocity (), density (), viscosity () for the ternary mixture of benzene + chloroform + cyclohexane in the whole range of composition has been carried out at various temperatures 303.15, 308.15 and 313.15K. From the measured parameters U, and , some derived parameters with molar enthalpy ( ) and apparent molar volume ( ) are also estimated. The decreasing trend of and with concentrations and other parameters are in increasing trend were observed. The trend of acoustical and physico-chemical parameters confirm the dynamics of molecules at higher temperature and the magnitude of intermolecular interactions among the constituents of the mixtures always reflects the nature of substance. The role of enthalpy and apparent molar volume has been used to determine their thermal response. The sign and magnitude of these properties are evident for the nature of interactions between component molecules.
在303.15K、308.15K和313.15K等不同温度下,对苯 + 氯仿 + 环己烷三元混合物在整个组成范围内的超声速()、密度()、粘度()进行了测定。根据测得的参数U、和,还估算了一些与摩尔焓()和表观摩尔体积()相关的导出参数。观察到随着浓度增加,和呈下降趋势,而其他参数呈上升趋势。声学和物理化学参数的趋势证实了较高温度下分子的动力学,混合物各成分之间分子间相互作用的大小始终反映了物质的性质。利用焓和表观摩尔体积的作用来确定它们的热响应。这些性质的符号和大小对于组分分子间相互作用的性质是明显的。