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小尺寸缺氧氧化钨纳米颗粒:通过在水中控制等离子体生成制备的机理研究

Small Nanosized Oxygen-Deficient Tungsten Oxide Particles: Mechanistic Investigation with Controlled Plasma Generation in Water for Their Preparation.

作者信息

Ishida Yohei, Motono Shingo, Doshin Wataru, Tokunaga Tomoharu, Tsukamoto Hiroki, Yonezawa Tetsu

机构信息

Division of Materials Science and Engineering, Faculty of Engineering, Hokkaido University, Kita 13 Nishi 8, Kita-ku, Sapporo, Hokkaido 060-8628, Japan.

Department of Quantum Engineering, Graduate School of Engineering, Nagoya University, Furo-cho, Chikusa-ku, Nagoya 464-8603, Japan.

出版信息

ACS Omega. 2017 Aug 29;2(8):5104-5110. doi: 10.1021/acsomega.7b00986. eCollection 2017 Aug 31.

DOI:10.1021/acsomega.7b00986
PMID:31457785
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6641750/
Abstract

Production of oxygen-deficient tungsten oxide nanoparticles with a diameter of around 10 nm have been successfully developed using a microwave-induced plasma in liquid technique. The prepared blue-green nanoparticles exhibit strong absorption in the visible region; thus, these could be efficient visible-light photocatalysts. The high-angle annular dark-field images revealed the dislocation of tungsten, which causes oxygen deficiencies.

摘要

利用液体中的微波诱导等离子体技术,已成功制备出直径约为10纳米的缺氧氧化钨纳米颗粒。制备出的蓝绿色纳米颗粒在可见光区域表现出强烈的吸收;因此,这些颗粒可能是高效的可见光光催化剂。高角度环形暗场图像揭示了钨的位错,这会导致氧缺陷。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/fb3917ea4d83/ao-2017-009866_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/8e47b8f4d21e/ao-2017-009866_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/b97f1605b746/ao-2017-009866_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/0f572a54fb90/ao-2017-009866_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/86431a6e9312/ao-2017-009866_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/e7b8c69d963a/ao-2017-009866_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/5c3493d76da0/ao-2017-009866_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/fb3917ea4d83/ao-2017-009866_0007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/8e47b8f4d21e/ao-2017-009866_0001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/b97f1605b746/ao-2017-009866_0002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/0f572a54fb90/ao-2017-009866_0003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/86431a6e9312/ao-2017-009866_0004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/e7b8c69d963a/ao-2017-009866_0005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/5c3493d76da0/ao-2017-009866_0006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/e1cd/6641750/fb3917ea4d83/ao-2017-009866_0007.jpg

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本文引用的文献

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Tungsten Oxides for Photocatalysis, Electrochemistry, and Phototherapy.用于光催化、电化学和光疗的氧化钨。
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Tungsten oxide single crystal nanosheets for enhanced multichannel solar light harvesting.氧化钨单晶纳米片用于增强多通道太阳光捕获。
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Ultrathin PEGylated W18O49 nanowires as a new 980 nm-laser-driven photothermal agent for efficient ablation of cancer cells in vivo.超支化聚乙二醇化 W18O49 纳米线作为一种新型的 980nm 激光驱动光热试剂,可高效消融体内癌细胞。
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Hexagonal mesocrystals formed by ultra-thin tungsten oxide nanowires and their electrochemical behaviour.由超细氧化钨纳米线形成的六方介晶及其电化学行为。
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