Li Xiao-Ru, Wang Xiao-Xiong, Ma Li-Chun, Peng Zhi, Yang Chao, Han Ping, Li Hong-Yan, Miao Yu-Cong, Long Yun-Ze, Song Guo-Jun
Institute of Polymer Materials, College of Physics, and College of Chemistry and Chemical Engineering, Qingdao University, No. 308 Ningxia Road, Qingdao 266071, China.
ACS Omega. 2018 Mar 30;3(3):3617-3621. doi: 10.1021/acsomega.8b00171. eCollection 2018 Mar 31.
One-dimensional (1D) Nd/Fe/polyamide 66 (Nd/Fe/PA66) three-layer coaxial nanocable arrays with high aspect ratio and highly anisotropic magnetization were successfully prepared via layer-by-layer deposition in the anodic aluminum oxide template. The morphology, chemical composition, and magnetic properties of Nd/Fe/PA66 nanocables were characterized by scanning electron microscopy, transmission electron microscopy, X-ray diffraction, and vibrating sample magnetometry . The effects of 1D nanocables on the magnetic properties of the assembled ordered arrays have been systematically investigated. The structural properties of these nanostructures are investigated as a function of the geometrical parameters. The magnetic anisotropy of Nd/Fe/PA66 nanocables has been significantly enhanced owing to the doped Nd that possesses a larger spin-orbital coupling and leads to a synergistic effect with Fe to enhance anisotropy energy.
通过在阳极氧化铝模板中逐层沉积,成功制备了具有高纵横比和高度各向异性磁化强度的一维(1D)钕/铁/聚酰胺66(Nd/Fe/PA66)三层同轴纳米电缆阵列。通过扫描电子显微镜、透射电子显微镜、X射线衍射和振动样品磁强计对Nd/Fe/PA66纳米电缆的形貌、化学成分和磁性能进行了表征。系统研究了一维纳米电缆对组装有序阵列磁性能的影响。研究了这些纳米结构的结构性质与几何参数的关系。由于掺杂的钕具有较大的自旋轨道耦合,并与铁产生协同效应以增强各向异性能量,Nd/Fe/PA66纳米电缆的磁各向异性得到了显著增强。