School of Life and Environmental Sciences, Faculty of Science, Engineering and Built Environment, Deakin University, Waurn Ponds, Victoria, 3216, Australia.
Centre for Regional and Rural Futures, Faculty of Science, Engineering and Built Environment, Deakin University, Waurn Ponds, Victoria, 3216, Australia.
Chem Commun (Camb). 2019 Sep 28;55(76):11474-11477. doi: 10.1039/c9cc05031k. Epub 2019 Sep 6.
Combining luminophores in ratios that compensate for energy transfer provides a readily selectable range of new emission colours for gel-based electrochemiluminescence devices (ECLDs). A novel blue ECLD luminophore is also introduced and shown to enhance the intensity of the conventional green emitter through a mixed annihilation ECL mechanism. Peak-to-peak voltages were minimised using asymmetric potential pulse sequences, which increased the longevity of the ECLD emission.
将荧光团以补偿能量转移的比例组合在一起，为基于凝胶的电化学发光器件（ECLD）提供了一系列可随时选择的新型发射颜色。还引入了一种新型蓝色 ECLD 荧光团，并通过混合湮灭 ECL 机制显示其增强了常规绿色发射器的强度。通过使用不对称电位脉冲序列使峰峰值电压最小化，从而延长了 ECLD 发射的寿命。
