Department of Chemical Sciences, Tezpur University, Napaam, 784028, Sonitpur, Assam, India.
Chem Commun (Camb). 2019 Sep 24;55(77):11547-11550. doi: 10.1039/c9cc05032a.
The effect of subtle structural distortions on single ion magnetic anisotropy of pentagonal bipyramidal Ni(ii) complexes was probed by magnetization measurements and theoretical calculations. Reducing structural distortion on the equatorial pentagonal plane and employing strong field ligands on axial coordination sites dramatically enhance the uniaxial magnetic anisotropy in pentagonal bipyramidal Ni(ii) complexes.
通过磁化率测量和理论计算研究了细微结构扭曲对五配位镍（II）配合物单离子各向异性的影响。减少赤道五边形平面上的结构扭曲并在轴向配位位置使用强场配体可显著增强五配位镍（II）配合物的单轴各向异性。
