Review of phosphorus attenuation in groundwater plumes from 24 septic systems.

This study reviews phosphorus (P) concentrations in groundwater plumes from 24 on-site wastewater treatment systems (septic systems) in Ontario, Canada. Site investigations were undertaken over a 30-year period from 1988 to 2018 at locations throughout the province that encompass a variety of domestic wastewater types and geologic terrain. The review focuses on P behaviour in the drainfield sediments and in the proximal plume zones, within 10 m of the drainfields, where plume conditions were generally at steady state. At these sites, mean soluble reactive phosphorus (SRP) values in the septic tank effluent ranged from 1.8 to 13.8 mg/L and averaged 8.4 mg/L. Phosphorus removal in the drainfields averaged 90% at sites where sediments were non calcareous (13 sites) and 66% at sites where sediments were calcareous (11 sites). Removal considering both the drainfields and proximal plume zones, averaged 97% at the non-calcareous sites and 69% at the calcareous sites, independent of the site age or loading rate. At 17 of the 24 sites, mean SRP concentrations in the proximal groundwater plumes (within 10 m) declined to ≤1 mg/L, which is a common treatment level for P at sewage treatment plants. Zones of P accumulation were present in almost all of the drainfields, where sand grains exhibited distinct secondary coatings containing P, demonstrating that mineral precipitation was likely the dominant cause of the P retention observed at these sites. This review confirms the often robust capacity for phosphorus removal in properly functioning septic systems. At the majority of these sites (17/24), P retention meets or exceeds removal that would normally be achieved during conventional sewage treatment. This challenges the necessity of avoiding septic system use in favor of communal sewer systems, when limiting phosphorus loading to nearby water courses is a principal or major concern.