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一种由细菌纤维素/铕复合物和纤维素纤维制成的高效耐用荧光纸。

A Highly Efficient and Durable Fluorescent Paper Produced from Bacterial Cellulose/Eu Complex and Cellulosic Fibers.

作者信息

Zhang Mingquan, Wu Xiao, Hu Zhenhua, Xiang Zhouyang, Song Tao, Lu Fachuang

机构信息

State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China.

Guangdong Engineering Research Center for Green Fine Chemicals, Guangzhou 510640, China.

出版信息

Nanomaterials (Basel). 2019 Sep 15;9(9):1322. doi: 10.3390/nano9091322.

Abstract

The general method of producing fluorescent paper by coating fluorescent substances onto paper base faces the problems of low efficiency and poor durability. Bacterial cellulose (BC) with its nanoporous structure can be used to stabilize fluorescent particles. In this study, we used a novel method to produce fluorescent paper by first making Eu/BC complex and then processing the complex and cellulosic fibers into composite paper sheets. For this composting method, BC can form very stable BC/Eu complex due to its nanoporous structure, while the plant-based cellulosic fibers reduce the cost and provide stiffness to the materials. The fluorescent paper demonstrated a great fluorescent property and efficiency. The ultraviolet absorbance or the fluorescent intensity of the Eu-BC fluorescent paper increased with the increase of Eu-BC content but remained little changed after Eu-BC content was higher than 5%. After folding 200 times, the fluorescence intensity of fluorescent paper decreased by only 0.7%, which suggested that the Eu-BC fluorescent paper has great stability and durability.

摘要

通过将荧光物质涂覆在纸基上制备荧光纸的常规方法面临效率低和耐久性差的问题。具有纳米多孔结构的细菌纤维素(BC)可用于稳定荧光颗粒。在本研究中,我们采用一种新方法制备荧光纸,首先制备Eu/BC复合物,然后将该复合物与纤维素纤维加工成复合纸张。对于这种复合方法,BC因其纳米多孔结构可形成非常稳定的BC/Eu复合物,而植物基纤维素纤维降低了成本并为材料提供了硬度。该荧光纸表现出优异的荧光性能和效率。Eu-BC荧光纸的紫外吸光度或荧光强度随Eu-BC含量的增加而增加,但在Eu-BC含量高于5%后变化不大。在折叠200次后,荧光纸的荧光强度仅下降了0.7%,这表明Eu-BC荧光纸具有很高的稳定性和耐久性。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/a390/6781274/770b308a1695/nanomaterials-09-01322-g001.jpg

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