由钴（II）和四唑衍生物组装而成的高稳定性含能配位聚合物。
Highly Stable Energetic Coordination Polymer Assembled with Co(II) and Tetrazole Derivatives.
作者信息
Wu Hui-Fang, Xu Jian-Gang, Lu Jian, Zheng Fa-Kun, Wang Shuai-Hua, Guo Guo-Cong
机构信息
State Key Laboratory of Structural Chemistry, Fujian Institute of Research on the Structure of Matter, Chinese Academy of Sciences, Fuzhou, Fujian 350002, P. R. China.
University of Chinese Academy of Sciences, Beijing 100039, P. R. China.
出版信息
ACS Omega. 2019 Sep 6;4(12):15107-15111. doi: 10.1021/acsomega.9b01971. eCollection 2019 Sep 17.
A solvothermal reaction of Co(CHCOO)·4HO and 5-mercapto-1-methyl-tetrazole (Hmmtz) in methanol (MeOH) yielded a one-dimensional solvent-free energetic coordination polymer, namely, [Co(mmtz)] , which was structurally characterized. The enthalpy of formation (Δ °) of (907 kJ mol) is much larger than that of commercial 2,4,6-trinitrotoluene (-59 kJ mol). The impact sensitivity and the friction sensitivity are greater than 40 J and 360 N, respectively, indicating that compound exhibits a potential application as a safe explosive. Temperature-dependent molar magnetic susceptibilities show that weak antiferromagnetic behavior exists in .
在甲醇（MeOH）中，Co(CHCOO)·4HO与5-巯基-1-甲基四唑（Hmmtz）进行溶剂热反应，得到了一种一维无溶剂含能配位聚合物，即[Co(mmtz)] ，并对其结构进行了表征。 （907 kJ mol）的生成焓远大于商用2,4,6-三硝基甲苯（-59 kJ mol）的生成焓。其撞击感度和摩擦感度分别大于40 J和360 N，表明该化合物作为安全炸药具有潜在应用价值。变温摩尔磁化率表明 中存在弱反铁磁行为。
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