College of Environmental Science and Engineering, Tongji University, Shanghai, China.
State Key Laboratory of Pollution Control and Resource Reuse, Tongji University, Shanghai, China.
Water Environ Res. 2020 Apr;92(4):579-587. doi: 10.1002/wer.1247. Epub 2019 Oct 11.
In this study, the inline coagulation was combined with ultrafiltration and nanofiltration (UF-NF) in a pilot study for Tai Lake water treatment. The results showed that the combination process was very effective for Tai Lake water treatment in terms of organic removal and membrane fouling control. With inline coagulation, no irreversible membrane fouling was observed for either UF or NF at fluxes of 65-90 and 22-26 L/(m hr), respectively. The membrane foulants were analyzed, and the results indicated that the low molecular weight fractions in the feed were main membrane fouling contributors for both UF and NF, where hydrophilic substances and proteins, as well as neutral substances and humic acids with polycarboxyl groups, contributed significantly to UF and NF membrane fouling, respectively. Compared with direct UF-NF filtration without coagulation, the coagulants could aggregate organic micromolecules for cake formation. With inline coagulation, the moving flocs could generate shear stress to scrub the membrane surface for fouling control of UF. Moreover, with inline coagulation, the organics removal efficiency could be further increased by 10%-20%. With NF, the permeate had a TOC concentration of less than 0.5 mg/L, satisfying the drinking water quality. Therefore, the coagulation-UF-NF is very useful for Tai Lake water treatment. PRACTITIONER POINTS: Inline coagulation-UF-NF for Tai Lake Water treatment is implemented. Inline coagulation can aggregate hydrophilic substances to reduce membrane fouling. Moving flocs produce shear stress for fouling control of UF-NF. Superior quality of permeate is achieved with the combined coagulation-UF-NF process.
在这项研究中,在线混凝被与超滤和纳滤(UF-NF)联合应用于太湖水处理的中试研究中。结果表明,就有机物去除和膜污染控制而言,该组合工艺对太湖水处理非常有效。在通量为 65-90 和 22-26 L/(m 小时)时,在线混凝对 UF 或 NF 都没有观察到不可逆的膜污染。对膜污染物进行了分析,结果表明,进料中的低分子量组分是 UF 和 NF 的主要膜污染贡献者,其中亲水性物质和蛋白质以及带多羧基的中性物质和腐殖酸分别对 UF 和 NF 膜污染有显著贡献。与未经混凝的直接 UF-NF 过滤相比,混凝剂可以聚集有机小分子形成滤饼。在线混凝时,移动絮体能产生剪切力擦洗膜表面,从而控制 UF 的污染。此外,通过在线混凝,有机物去除效率可进一步提高 10%-20%。对于 NF,透过液的 TOC 浓度小于 0.5mg/L,满足饮用水水质要求。因此,混凝-UF-NF 非常适用于太湖水处理。