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来自可再生二次原料的混合纤维素-二氧化硅材料:一种环保方法。

Hybrid Cellulose-Silica Materials from Renewable Secondary Raw Resources: An Eco-friendly Method.

作者信息

Vasquez-Zacarias Leticia, Ponce-Peña Patricia, Pérez-López Tezozomoc, Franco-Urquiza Edgar A, Ramirez-Galicia Guillermo, Poisot Martha

机构信息

Universidad del Papaloapan Circuito Central 200, Parque Industrial Tuxtepec Oaxaca C.P. 68301 Mexico.

Universidad Juárez del Estado de Durango Facultad de Ciencias Químicas Av. Veterinaria S/N Circuito Universitario Durango Dgo. C.P. 34120 Mexico.

出版信息

Glob Chall. 2018 Jun 19;2(7):1700119. doi: 10.1002/gch2.201700119. eCollection 2018 Jul.

Abstract

Hybrid organic-inorganic materials based on cellulose matrix and silica particles are obtained from wastes of the local paper recycling mill and sugarcane mill as renewable secondary raw materials. The performance comparison of these hybrid materials made from secondary raw materials against the materials made from pure, raw sources is discussed. The Fourier transform infrared spectra show that cellulose features prevail even at 43 wt% silica nanoparticles in the hybrid materials. Such a high content of silica originated from sugarcane bagasse ash and hollow glass microspheres contributes to the high thermal stability of the final composites, as seen by thermogravimetric analysis with very low water absorption. This one-step approach of biobased hybrid materials represents an excellent way to produce high-performance materials with high content of inorganic nanoparticles for a wide variety of applications like energy efficient building material completely cement-free.

摘要

基于纤维素基质和二氧化硅颗粒的有机-无机杂化材料是从当地造纸厂和甘蔗厂的废料中获取的可再生二次原料制成的。文中讨论了由二次原料制成的这些杂化材料与由纯原料制成的材料的性能比较。傅里叶变换红外光谱表明,即使在杂化材料中二氧化硅纳米颗粒含量为43 wt%时,纤维素特征仍然占主导。通过热重分析可以看出,源自甘蔗渣灰和中空玻璃微球的如此高含量的二氧化硅有助于最终复合材料具有高热稳定性,且吸水率极低。这种生物基杂化材料的一步法是生产具有高含量无机纳米颗粒的高性能材料的绝佳方法,可用于多种应用,如完全无水泥的节能建筑材料。

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