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两步法制备FeCo/ZnO复合材料及其微波吸收性能的增强

The Preparation of FeCo/ZnO Composites and Enhancement of Microwave Absorbing Property by Two-Step Method.

作者信息

Gao Ka, Zhao Junliang, Bai Zhongyi, Song Wenzheng, Zhang Rui

机构信息

School of Materials Science and Engineering, Zhengzhou University of Aeronautics, Zhengzhou 450015, China.

Henan Key Laboratory of Aeronautical Material and Application Technology, Zhengzhou 450015, China.

出版信息

Materials (Basel). 2019 Oct 6;12(19):3259. doi: 10.3390/ma12193259.

DOI:10.3390/ma12193259
PMID:31590439
原文链接:https://pmc.ncbi.nlm.nih.gov/articles/PMC6804276/
Abstract

In this paper, the flower-like FeCo/ZnO composites were successfully firstly prepared by a two-step method, and their microstructures and microwave absorbing properties were characterized. The results show that with an increase of temperature, the content of ZnO loaded on a FeCo/ZnO composite surface was increased. The optimal reflection loss (RL) value can be reached around -53.81 dB at 9.8 GHz, which is obviously superior to results of previous studies and reports, and its effective bandwidth (RL < -10 dB) is 3.8 GHz in the frequency range of 8.7-11.8 GHz with a matching thickness of 1.9 mm. We considered that a large number of lamellar and rod-like ZnO loaded on nano-FeCo single-phase solid solution by two-step method can significantly improve the electromagnetic wave absorption properties.

摘要

本文首次采用两步法成功制备了花状FeCo/ZnO复合材料,并对其微观结构和吸波性能进行了表征。结果表明,随着温度的升高,负载在FeCo/ZnO复合材料表面的ZnO含量增加。在9.8 GHz时,最佳反射损耗(RL)值可达-53.81 dB左右,明显优于以往的研究和报道结果,在8.7-11.8 GHz频率范围内,其有效带宽(RL < -10 dB)为3.8 GHz,匹配厚度为1.9 mm。我们认为,通过两步法负载在纳米FeCo单相固溶体上的大量片状和棒状ZnO可显著提高电磁波吸收性能。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/8b25dd7b96a8/materials-12-03259-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/21a6b9a8f9b2/materials-12-03259-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/b8f37bfa60fd/materials-12-03259-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/30e1bdc2cc1f/materials-12-03259-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/8807631d0926/materials-12-03259-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/91780a7f4c28/materials-12-03259-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/ea3aabbacd80/materials-12-03259-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/06960f764830/materials-12-03259-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/8b25dd7b96a8/materials-12-03259-g008.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/21a6b9a8f9b2/materials-12-03259-g001.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/b8f37bfa60fd/materials-12-03259-g002.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/30e1bdc2cc1f/materials-12-03259-g003.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/8807631d0926/materials-12-03259-g004.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/91780a7f4c28/materials-12-03259-g005.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/ea3aabbacd80/materials-12-03259-g006.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/06960f764830/materials-12-03259-g007.jpg
https://cdn.ncbi.nlm.nih.gov/pmc/blobs/8e61/6804276/8b25dd7b96a8/materials-12-03259-g008.jpg

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本文引用的文献

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Prussian blue analogues derived magnetic FeCo alloy/carbon composites with tunable chemical composition and enhanced microwave absorption.普鲁士蓝类似物衍生的具有可调化学成分和增强微波吸收的磁性 FeCo 合金/碳复合材料。
J Colloid Interface Sci. 2018 Mar 15;514:10-20. doi: 10.1016/j.jcis.2017.12.013. Epub 2017 Dec 6.
2
Fabrication of a Nano-ZnO/Polyethylene/Wood-Fiber Composite with Enhanced Microwave Absorption and Photocatalytic Activity via a Facile Hot-Press Method.通过简便的热压法制备具有增强微波吸收和光催化活性的纳米氧化锌/聚乙烯/木纤维复合材料
Materials (Basel). 2017 Nov 3;10(11):1267. doi: 10.3390/ma10111267.
3
Temperature-Dependent Magnetic Response of Antiferromagnetic Doping in Cobalt Ferrite Nanostructures.
钴铁氧体纳米结构中反铁磁掺杂的温度依赖性磁响应
Nanomaterials (Basel). 2016 Apr 18;6(4):73. doi: 10.3390/nano6040073.
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Carbon coated Co-SiC nanocomposite with high-performance microwave absorption.具有高性能微波吸收能力的碳包覆 Co-SiC 纳米复合材料。
Phys Chem Chem Phys. 2013 Oct 14;15(38):16104-10. doi: 10.1039/c3cp52735b. Epub 2013 Aug 28.
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Preparation and electromagnetic properties of core/shell polystyrene@polypyrrole@nickel composite microspheres.核/壳聚苯乙烯@聚吡咯@镍复合微球的制备及电磁性能。
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