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径迹蚀刻动力学对离子路径周围化学反应性的依赖性。

Dependence of track etching kinetics on chemical reactivity around the ion path.

作者信息

Gorbunov S A, Rymzhanov R A, Volkov A E

机构信息

P. N. Lebedev Physical Institute of the Russian Academy of Sciences, Leninskij pr. 53, 119991, Moscow, Russia.

Joint Institute for Nuclear Research, Joliot-Curie 6, 141980, Dubna, Moscow Region, Russia.

出版信息

Sci Rep. 2019 Oct 25;9(1):15325. doi: 10.1038/s41598-019-51748-y.

Abstract

Etching kinetics of swift heavy ions (SHI) tracks in olivine is investigated in frame of experimentally verified numerical approach. The model takes into account variation of induced chemical reactivity of the material around the whole ion trajectory with the nanometric accuracy. This enables a quantitative description of wet chemical etching of SHI tracks of different lengths and orientations towards to the sample surface. It is demonstrated that two different modes of etching, governed by diffusion of etchant molecules and by their reaction with the material must be observed in experiments using techniques with different resolution thresholds. Applicability limits of the optical microscopy for detection of heavy ion parameters by measuring of the lengthwise etching rates of the ion track are discussed.

摘要

在经过实验验证的数值方法框架内,研究了快重离子(SHI)在橄榄石中的径迹蚀刻动力学。该模型考虑了整个离子轨迹周围材料诱导化学反应性的纳米级精度变化。这使得能够对不同长度和相对于样品表面不同取向的SHI径迹的湿化学蚀刻进行定量描述。结果表明,在使用具有不同分辨率阈值的技术进行的实验中,必须观察到由蚀刻剂分子扩散及其与材料反应所控制的两种不同蚀刻模式。讨论了通过测量离子径迹的纵向蚀刻速率来检测重离子参数的光学显微镜的适用范围。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/705a/6814710/aff95e963dcd/41598_2019_51748_Fig1_HTML.jpg

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