基于碳水化合物的手性碘芳烃催化剂：通过改进催化剂设计的发展进行调查。
Carbohydrate-Based Chiral Iodoarene Catalysts: A Survey through the Development of an Improved Catalyst Design.
机构信息
Institute of Organic Chemistry, University of Tuebingen, Auf der Morgenstelle 18, 72076 Tuebingen, Germany.
Institute of Inorganic Chemistry, University of Tuebingen, Auf der Morgenstelle 18, 72076 Tuebingen, Germany.
出版信息
Molecules. 2019 Oct 28;24(21):3883. doi: 10.3390/molecules24213883.
Iodoarene catalysts can be applied in versatile reactions, for instance in the construction of complex chiral molecules via dearomatization of simple aromatic compounds. Recently, we reported the synthesis of the first carbohydrate-based chiral iodoarene catalysts and their application in asymmetric catalysis. Here we describe the synthesis of some new and improved catalysts. An account on how we got to the improved catalyst design, as well as the X-ray structure of one of the carbohydrate-based iodoarenes, is given.
碘芳烃催化剂可应用于多种反应，例如通过简单芳香化合物的去芳构化来构建复杂的手性分子。最近，我们报道了首例基于糖类的手性碘芳烃催化剂的合成及其在手性催化中的应用。在此，我们描述了一些新型改进催化剂的合成。本文介绍了我们如何进行改进的催化剂设计，以及其中一种基于糖类的碘芳烃的 X 射线结构。
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