通过自组装制备诺-瓜环超分子聚合物。
Fabrication of nor-seco-cucurbit[10]uril based supramolecular polymers via self-sorting.
机构信息
Key Lab of Organic Optoelectronics and Molecular Engineering, Department of Chemistry, Tsinghua University, Beijing, 100084, China.
出版信息
Chem Commun (Camb). 2019 Nov 14;55(92):13836-13839. doi: 10.1039/c9cc07127j.
PMID:31663546
Abstract
A nor-seco-CB[10] (ns-CB[10]) based linear supramolecular polymer is firstly fabricated via self-sorting strategy. Through self-sorting of the monomer, ns-CB[10] and CB[7], the unfavorable factors for supramolecular polymerization are avoided. Therefore, supramolecular polymer with high molecular weight is successfully fabricated, and the molecular weight can be controllably regulated.
摘要
一种基于 nor-seco-CB[10]（ns-CB[10]）的线性超分子聚合物通过自组装策略首次制备。通过单体的自组装，ns-CB[10]和 CB[7]避免了超分子聚合的不利因素。因此，成功制备了具有高分子量的超分子聚合物，并且分子量可以得到可控调节。
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