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高CaO粉煤灰和硫酸盐活化剂作为无水泥灌浆材料细粘结剂的效果

Effects of High CaO Fly Ash and Sulfate Activator as a Finer Binder for Cementless Grouting Material.

作者信息

Lee Jaehyun, Lee Taegyu

机构信息

Technology Research and Development Institute, Daelim Industrial, Jongno-Gu, Seoul 03152, Korea.

出版信息

Materials (Basel). 2019 Nov 7;12(22):3664. doi: 10.3390/ma12223664.

Abstract

The effects or high CaO fly ash and sulfate activator on cementless grouting material were investigated through Labiles Waterglass (LW) grouting applied at an actual construction field. Circulating fluidized bed combustion ash was used as CaO fly ash, and petro cokes desulfurization gypsum was used as sulfate activator. Cementless grouting material (CGM) could decrease the gel time by about 16.7% compared with ordinary Portland cement (OPC). This characteristic improved the average daily workload and construction period per meter by about 13.5% with CGM. Furthermore, when constructing 1000 holes of LW grouting, the construction time could be reduced by 19 days (20% of the total construction period of LW grouting). Meanwhile, CGM could increase the homogel strength by about 48.4% after 28 days compared with OPC. After X-ray diffraction analysis and scanning electron microscope analysis, CGM was found to produce cement hydrate by chemical reaction mechanism of high CaO fly ash and sulfate activator, even though cement was not used. The matrix structure properties of CGM and OPC specimens were similar, but CGM, with 134.3% fineness, exhibited higher compressive strength and lower air permeability than OPC. As a result, CGM could reduce the leakage length per square meter by 74.4% compared with OPC. Using CGM as a substitute for OPC in LW grouting in actual sites could be beneficial in terms of securing construction speed and durability, as well as reducing CO emissions due to reduction of OPC usage.

摘要

通过在实际施工现场应用不稳定水玻璃(LW)灌浆,研究了高CaO粉煤灰和硫酸盐活化剂对无水泥灌浆材料的影响。循环流化床燃烧灰用作CaO粉煤灰,石油焦脱硫石膏用作硫酸盐活化剂。与普通硅酸盐水泥(OPC)相比,无水泥灌浆材料(CGM)可使凝胶时间缩短约16.7%。这一特性使使用CGM时每米的平均日工作量和施工周期提高了约13.5%。此外,在进行1000个LW灌浆孔施工时,施工时间可减少19天(占LW灌浆总施工周期的20%)。同时,与OPC相比,CGM在28天后可使均匀凝胶强度提高约48.4%。经过X射线衍射分析和扫描电子显微镜分析,发现即使不使用水泥,CGM也能通过高CaO粉煤灰和硫酸盐活化剂的化学反应机制生成水泥水化物。CGM和OPC试件的基体结构性能相似,但CGM的细度为134.3%,其抗压强度更高,透气率更低。结果,与OPC相比,CGM可使每平方米的渗漏长度减少74.4%。在实际现场的LW灌浆中使用CGM替代OPC,在确保施工速度和耐久性方面可能是有益的,同时由于减少了OPC的使用,还能减少二氧化碳排放。

https://cdn.ncbi.nlm.nih.gov/pmc/blobs/c745/6888419/53504aad53c1/materials-12-03664-g001.jpg

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