Institute for Chemical Research, Kyoto University Uji, Kyoto 611-0011, Japan.
J Chem Phys. 2019 Nov 7;151(17):170902. doi: 10.1063/1.5125628.
Metal halide perovskite semiconductors fabricated with simple low-temperature solution processes are a unique class of materials anticipated for use in photonic devices such as solar cells, light-emitting diodes, and light modulators. The metal halide perovskites in the form of nanocrystals are particularly attracting attention as novel functional materials because of their exceptionally high luminescence efficiencies and wide range of possible luminescence wavelengths. By combining different optical characterization techniques, that is, single-dot spectroscopy, photon correlation spectroscopy, femtosecond transient absorption spectroscopy, and time-resolved photoluminescence spectroscopy, we study the dynamics of excitons, trions, and biexcitons in perovskite nanocrystals. Here, we provide a concise review of recent developments in this research field with a focus on trions in lead halide perovskite nanocrystals. A deep understanding of trion dynamics is especially important because they determine the luminescence properties of nanocrystals and are related to the ionization processes of nanocrystals.
采用简单低温溶液处理方法制备的卤化金属钙钛矿半导体是一类独特的材料,有望用于光子器件,如太阳能电池、发光二极管和光调制器。纳米晶形式的卤化金属钙钛矿作为新型功能材料特别引人关注,因为它们具有极高的发光效率和广泛的可能发光波长。通过结合不同的光学特性分析技术,即单分子光谱学、光子相关光谱学、飞秒瞬态吸收光谱学和时间分辨光致发光光谱学,我们研究了钙钛矿纳米晶中激子、电子空穴对和双激子的动力学。本文重点介绍了卤化铅钙钛矿纳米晶中电子空穴对的最新研究进展,提供了该研究领域的简明综述。深入了解电子空穴对动力学尤为重要,因为它们决定了纳米晶的发光特性,并与纳米晶的电离过程有关。